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N-Methyl-1-(methylthio)-2-nitroethylen-1-amine

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N-Methyl-1-(methylthio)-2-nitroethylen-1-amine Basic information

Product Name:
N-Methyl-1-(methylthio)-2-nitroethylen-1-amine
Synonyms:
  • N-Methyl-1-(methylth
  • 1-(Methylthio)-2-nitro-N-MethylethyleneaMine
  • 2-(Methylthio)-2-(MethylaMino)-1-nitroethene
  • Nizatidine EP IMpurity B
  • (E)-N-Methyl-1-(Methylthio)-2-nitroethenaMine
  • Methyl (1Z)-N-Methyl-2-nitroethaniMidothioate
  • NED
  • N-METHYL-1-METHYLTHIO-2-NITROETHENAMINE
CAS:
61832-41-5
MF:
C4H8N2O2S
MW:
148.18
EINECS:
263-266-9
Product Categories:
  • Intermediates
  • Sulfur & Selenium Compounds
  • Sulfur Compounds
  • Amines
  • (intermediate of ranitidine)
  • PHARMACEUTICAL INTERMEDIATES
  • Anilines, Aromatic Amines and Nitro Compounds
  • Organic Building Blocks
  • Sulfides/Disulfides
Mol File:
61832-41-5.mol
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N-Methyl-1-(methylthio)-2-nitroethylen-1-amine Chemical Properties

Melting point:
112-118 °C (lit.)
Boiling point:
236.5±35.0 °C(Predicted)
Density 
1.199±0.06 g/cm3(Predicted)
storage temp. 
2-8°C, protect from light, stored under nitrogen
solubility 
Chloroform, Methanol (Sparingly)
pka
0.86±0.70(Predicted)
form 
powder to crystal
color 
Light orange to Yellow to Green
BRN 
2828017
InChI
InChI=1S/C4H8N2O2S/c1-5-4(9-2)3-6(7)8/h3,5H,1-2H3
InChIKey
YQFHPXZGXNYYLD-UHFFFAOYSA-N
SMILES
C(NC)(SC)=C[N+]([O-])=O
CAS DataBase Reference
61832-41-5(CAS DataBase Reference)
NIST Chemistry Reference
Ethenamine, n-methyl-1-(methylthio)-2-nitro-(61832-41-5)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN 3335
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29309090

MSDS

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N-Methyl-1-(methylthio)-2-nitroethylen-1-amine Usage And Synthesis

Chemical Properties

Yellow Solid

Uses

Intermediate in the preparation of Ranitidine and Nizatidine.

Uses

(E) N-methyl-1-(methylthio)-2-nitroethenamine) (NMSM) may be used for the following syntheses:

  • pyrano[2,3-c]pyrazol-6-amines
  • 6-methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine

N-Methyl-1-(methylthio)-2-nitroethylen-1-amine Preparation Products And Raw materials

Raw materials

N-Methyl-1-(methylthio)-2-nitroethylen-1-amineSupplier

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