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alpha-L-Rhamnose

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alpha-L-Rhamnose Basic information

Product Name:
alpha-L-Rhamnose
Synonyms:
  • 6-Deoxyhexopyranose
  • 6-deoxy-l-mannos
  • 6-Deoxymannose
  • Isoducitol
  • L-Mannopyranose, 6-deoxy-
  • Locaose
  • Mannose, 6-deoxy-
  • Rhamnopyranose
CAS:
3615-41-6
MF:
C6H12O5
MW:
164.16
EINECS:
222-793-4
Product Categories:
  • FINE Chemical & INTERMEDIATES
  • Biochemistry
  • Deoxysugars
  • Rhamnose
  • Sugars
  • Dextrins、Sugar & Carbohydrates
  • Plant extracts
  • Herb extract
  • bc0001
Mol File:
3615-41-6.mol
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alpha-L-Rhamnose Chemical Properties

Melting point:
91-95°C
Boiling point:
251.61°C (rough estimate)
Density 
1.3058 (rough estimate)
refractive index 
1.6400 (estimate)
FEMA 
3730 | L-RHAMNOSE
storage temp. 
2-8°C
form 
Solid
pka
12.50±0.20(Predicted)
color 
White to off-white
Odor
at 100.00 %. odorless
Odor Type
odorless
Water Solubility 
521.5g/L(40 ºC)
Merck 
8172
LogP
-2.17 at 25℃
CAS DataBase Reference
3615-41-6(CAS DataBase Reference)
NIST Chemistry Reference
L-Mannose, 6-deoxy-(3615-41-6)
EPA Substance Registry System
L-Mannose, 6-deoxy- (3615-41-6)
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alpha-L-Rhamnose Usage And Synthesis

Chemical Properties

L-Rhamnose has no odor, but has a very sweet taste.

Chemical Properties

White crystals. For equilibrium mixture optical rotation is +9.18 degrees. Very soluble in water and in methanol; soluble in absolute alcohol.

Uses

Synthetic sweetener research.

Definition

ChEBI: The acyclic form of L-rhamnose.

Flammability and Explosibility

Not classified

Purification Methods

Crystallise the rhamnose from H2O or EtOH. It crystallises easily as the monohydrate by evaporating a solution in MeOH (90%) and H2O (10%). It is also purified by dissolving in a small volume of EtOH, adding a few drops of H2O and cooling. 1H NMR in D2O at 44o contains 60% -pyranose and 40% -pyranose forms [Angyal Adv Carbohydr Chem 42 15 1984.] [Smith J Chem Soc 1035 1940, McGeachin & Beevers Acta Cryst 10 227,230 197, Beilstein 1 IV 4261.]

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