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(2S)-(+)-Glycidyl tosylate

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(2S)-(+)-Glycidyl tosylate Basic information

Product Name:
(2S)-(+)-Glycidyl tosylate
Synonyms:
  • (2S)-Oxiran-2-ylmethyl 4-methylbenzenesulphonate 98%
  • (S)-Glycidyl Tosylate,99%e.e.
  • 2-Oxiranylmethyl 4-methylbenzenesulfonate
  • 4-methylbenzenesulfonate,(s)-oxiranemethano
  • (S)-Oxiran-2-ylMethyl 4-Methylbenzenesulfonate
  • (2S)-2-OxiraneMethanol 2-(4-Methylbenzenesulfonate)
  • (S)-(2,3-Epoxypropan-1-yl) 4-Methylbenzenesulfonate
  • (S)-Oxiran-2-ylMethyl Toluene-4-sulfonate
CAS:
70987-78-9
MF:
C10H12O4S
MW:
228.26
EINECS:
417-210-7
Product Categories:
  • Carbohydrates & Derivatives
  • Sulfur & Selenium Compounds
  • Phenyls & Phenyl-Het
  • chiral
  • CHIRAL COMPOUNDS
  • Aromatics
  • Chiral Compound
  • Phenyls & Phenyl-Het
Mol File:
70987-78-9.mol
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(2S)-(+)-Glycidyl tosylate Chemical Properties

Melting point:
46-49 °C(lit.)
alpha 
17 º (c=2.5, CHCl3)
Boiling point:
340.07°C (rough estimate)
Density 
1.3749 (rough estimate)
refractive index 
1.5400 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Dioxane (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Fluffy Powder
color 
White
Water Solubility 
decomposes
BRN 
3592143
CAS DataBase Reference
70987-78-9(CAS DataBase Reference)
NIST Chemistry Reference
(2S)-glycidyl tosylate(70987-78-9)
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Safety Information

Hazard Codes 
T,N,Xi
Risk Statements 
45-41-43-51/53-68
Safety Statements 
53-45-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
RR0510050
3-10-21
HazardClass 
9
PackingGroup 
III
HS Code 
29109000

MSDS

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(2S)-(+)-Glycidyl tosylate Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.

Uses

(2S)-(+)-Glycidyl tosylate is protected Glycidol, used as an intermediate in the preparation of neurochemicals.

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