ChemicalBook > Product Catalog > Organic Chemistry > Alcohols,Phenols,Phenol alcohols > (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Basic information
- Product Name:
- (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
- Synonyms:
-
- [(4S,5S)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-dinaphthalen-1-ylmethanol
- (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
- (4S-TRANS)-2,2-DIMETHYL-A,A,A',A'-TETRA( 1-NAPHTHYL)-1,3-DIOXOLANEDIMETHANOL, 99%
- (4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol
- (4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-nephthyl)-1,3-dioxolane-4,5-dimethanol
- (4S-trans)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol 99%
- (4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-1,3-Dioxolane-4,5-dimethanol
- (4S,5S)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol,98%
- CAS:
- 171086-52-5
- MF:
- C47H38O4
- MW:
- 666.8
- Product Categories:
-
- Chiral Oxygen
- TADDOL Series
- Chiral Catalysts, Ligands, and Reagents
- Privileged Ligands and Complexes
- TADDOLs
- Mol File:
- 171086-52-5.mol
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(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Chemical Properties
- Melting point:
- 200 °C (dec.)(lit.)
- Density
- 1.269±0.06 g/cm3(Predicted)
- pka
- 12.00±0.29(Predicted)
- optical activity
- [α]20/D +280°, c = 1 in ethyl acetate
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(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Usage And Synthesis
Uses
(4S-trans)-2,2-Dimethyl-α,α,α′,α′-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol, also known as TADDOL, is a chiral auxiliary that can be used:
- For the highly enantioselective addition of primary alkyl Grignards to ketones.
- As an organocatalyst for the activation of carbonyl functionality in vinylogous addition reaction of an aldehyde.
- As a chiral dopant in the preparation of cholesteric liquid crystal (CLC) having an aggregation-induced-emission dye.
(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&Supplier
Energy Chemical
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- 021-021-58432009 400-005-6266
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Daicel Chiral Technologies (China)CO.,LTD
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- 021-50460086-9 15921403865
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Tianjin Derchemist Science & Technology Co., Ltd.
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- 22-58627059 13920586291
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Bide Pharmatech Ltd.
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- 400-164-7117 13681763483
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Sigma-Aldrich
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