N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Basic information
- Product Name:
- N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
- Synonyms:
-
- BIPOL-A1(R), (R,R)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(R)-1-phenylethyl]phosphoramidite
- N,N-bis[(1S)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
- N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%
- N,N-Bis[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosp hepin-6-amine,99%e.e.
- N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine,97%
- N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
- Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1R)-1-phenylethyl]-
- N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- CAS:
- 500103-26-4
- MF:
- C28H26NO2P
- MW:
- 439.49
- Product Categories:
-
- Chiral Phosphine
- CPN
- phosphine-amine ligand
- Mol File:
- 500103-26-4.mol
More
Less
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties
- Melting point:
- 99-102 °C
- Boiling point:
- 578.4±53.0 °C(Predicted)
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- pka
- -0.31±0.20(Predicted)
- form
- Powder
- color
- white
- Sensitive
- moisture sensitive
- InChI
- 1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
- InChIKey
- JISGHECLGYELKD-UHFFFAOYSA-N
- SMILES
- C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
More
Less
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Usage And Synthesis
Uses
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the asymmetric hydrovinylation of 1,3-diene.
- In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.
reaction suitability
reaction type: click chemistry
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][Supplier
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18934348241
- sales4.gd@hwrkchemical.com
Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
Tianjin Derchemist Science & Technology Co., Ltd.
- Tel
- 22-58627059 13920586291
- zdcomcon@126.com
Sigma-Aldrich
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
Shanghai Chiral bio-compound co., Ltd.
- Tel
- 021-5068 3667/17749785980/1029026415; 17749785980
- 1029026415@qq.com
More
Less
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][(500103-26-4)Related Product Information
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE
- N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][