Basic information Safety Supplier Related

N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][

Basic information Safety Supplier Related

N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Basic information

Product Name:
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
Synonyms:
  • BIPOL-A1(R), (R,R)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(R)-1-phenylethyl]phosphoramidite
  • N,N-bis[(1S)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
  • N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%
  • N,N-Bis[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosp hepin-6-amine,99%e.e.
  • N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine,97%
  • N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
  • Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1R)-1-phenylethyl]-
CAS:
500103-26-4
MF:
C28H26NO2P
MW:
439.49
Product Categories:
  • Chiral Phosphine
  • CPN
  • phosphine-amine ligand
Mol File:
500103-26-4.mol
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N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties

Melting point:
99-102 °C
Boiling point:
578.4±53.0 °C(Predicted)
pka
-0.31±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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Safety Information

WGK Germany 
3
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N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ Usage And Synthesis

Uses

N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

  • In the asymmetric hydrovinylation of 1,3-diene.
  • In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.

N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][Supplier

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