Ferric acetylacetonate
Ferric acetylacetonate Basic information
- Product Name:
- Ferric acetylacetonate
- Synonyms:
-
- Acetylacetone Iron(III) Salt Ferric(III) Acetylacetonate Iron(III) Acetylacetonate
- TRIS(2,4-PENTANEDIONATO)IRON
- TRIS(2,4-PENTANEDIONATO)IRON(3)
- TRIS(2,4-PENTANEDIONATO)IRON(III)
- TRIS(ACETYLACETONATO)IRON(III)
- (Acetylacetonato)iron(iii)
- (OC-6-11)-tris(2,4-pentanedionato-O,o’)-iron
- 4-pentanedionato-o,o’)-tris((oc-6-11)-iro
- CAS:
- 14024-18-1
- MF:
- C15H21FeO6
- MW:
- 353.17
- EINECS:
- 237-853-5
- Product Categories:
-
- metal beta-diketonate complexes
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Environmentally-friendly Oxidation
- Fe (Iron) Compounds
- Homogeneous Catalysts
- Organometallics
- Metal Complexes
- Synthetic Organic Chemistry
- Transition Metal Complexes (Environmentally-friendly Oxidation)
- Transition Metal Compounds
- 14024-18-1
- Mol File:
- 14024-18-1.mol
Ferric acetylacetonate Chemical Properties
- Melting point:
- 180-182 °C (dec.)(lit.)
- Boiling point:
- 110°C 2mm
- Density
- 5.24 g/mL at 25 °C(lit.)
- vapor pressure
- 2.6 hPa (110 °C)
- storage temp.
- Store below +30°C.
- solubility
- Soluble in toluene.
- form
- Powder
- color
- Red
- Specific Gravity
- 5.24
- Water Solubility
- 2 g/L (20 ºC)
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 4157960
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 - Stability:
- Stable. Incompatible with strong bases, strong oxidizing agents.
- LogP
- 0.4 at 20℃
- NIST Chemistry Reference
- Iron tris(acetylacetonate)(14024-18-1)
- EPA Substance Registry System
- Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1)
MSDS
- Language:English Provider:Iron(III) acetylacetonate
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Ferric acetylacetonate Usage And Synthesis
Chemical Properties
dark red powder or Red-orange orthorhombic crystal, slightly soluble in water and heptane, easily soluble in ethanol, benzene, chloroform, acetone and ether. Solubility at 25°C: water 0.16, methanol 9.5, toluene 21.3, benzene 52.5.
Uses
Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
Uses
Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4
Uses
Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Preparation
Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.
General Description
This product has been enhanced for catalytic efficiency.
Flammability and Explosibility
Not classified
Purification Methods
When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.]
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Ferric acetylacetonate(14024-18-1)Related Product Information
- Ferric chloride
- Ammonium ferric citrate
- Acetylacetone
- Vanadyl acetylacetonate
- Hematite
- Bis(acetylacetonato)cobalt
- Cobaltic acetylacetonate
- Platinum bis(acetylacetonate)
- Aluminum acetylacetonate
- Nickel(II) acetylacetonate
- Iridium(III) acetylacetonate
- sodium 4-oxovalerate
- Calcium acetylacetonate
- COBALT(II) ACETYLACETONATE
- Ethyl levulinate
- Methyl levulinate
- Levulinic acid
- BARIUM ACETYLACETONATE HYDRATE