ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic iron > Ferric acetylacetonate
Ferric acetylacetonate
Ferric acetylacetonate Basic information
- Product Name:
- Ferric acetylacetonate
- Synonyms:
-
- Acetylacetone Iron(III) Salt Ferric(III) Acetylacetonate Iron(III) Acetylacetonate
- TRIS(2,4-PENTANEDIONATO)IRON
- TRIS(2,4-PENTANEDIONATO)IRON(3)
- TRIS(2,4-PENTANEDIONATO)IRON(III)
- TRIS(ACETYLACETONATO)IRON(III)
- (Acetylacetonato)iron(iii)
- (OC-6-11)-tris(2,4-pentanedionato-O,o’)-iron
- 4-pentanedionato-o,o’)-tris((oc-6-11)-iro
- CAS:
- 14024-18-1
- MF:
- C15H21FeO6
- MW:
- 353.17
- EINECS:
- 237-853-5
- Product Categories:
-
- metal beta-diketonate complexes
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Environmentally-friendly Oxidation
- Fe (Iron) Compounds
- Homogeneous Catalysts
- Metal Complexes
- Synthetic Organic Chemistry
- Transition Metal Complexes (Environmentally-friendly Oxidation)
- Transition Metal Compounds
- Organometallics
- Mol File:
- 14024-18-1.mol
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Ferric acetylacetonate Chemical Properties
- Melting point:
- 180-182 °C (dec.)(lit.)
- Boiling point:
- 110°C 2mm
- Density
- 5.24 g/mL at 25 °C(lit.)
- vapor pressure
- 2.6 hPa (110 °C)
- storage temp.
- Store below +30°C.
- solubility
- Soluble in toluene.
- form
- Powder
- Specific Gravity
- 5.24
- color
- Red
- Water Solubility
- 2 g/L (20 ºC)
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 4157960
- Stability:
- Stable. Incompatible with strong bases, strong oxidizing agents.
- NIST Chemistry Reference
- Iron tris(acetylacetonate)(14024-18-1)
- EPA Substance Registry System
- Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1)
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MSDS
- Language:English Provider:Iron(III) acetylacetonate
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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Ferric acetylacetonate Usage And Synthesis
Chemical Properties
dark red powder
Uses
Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
Preparation
Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.
Purification Methods
When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.]
Ferric acetylacetonateSupplier
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Ferric acetylacetonate(14024-18-1)Related Product Information
- Nickel(II) acetylacetonate
- Vanadyl acetylacetonate
- Bis(acetylacetonato)cobalt
- Ferric acetylacetonate
- copper (Ⅱ) acetylacetonate
- titanium (Ⅳ) acetylacetonate
- Ferric chloride
- Ammonium ferric citrate
- Acetylacetone
- Pyruvic acid
- Acetone
- Acetaldehyde
- Cobaltic acetylacetonate
- Platinum bis(acetylacetonate)
- Aluminum acetylacetonate
- pig iron
- Hematite
- ACETYLACETONATE