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Ferric acetylacetonate

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Ferric acetylacetonate Basic information

Product Name:
Ferric acetylacetonate
Synonyms:
  • Acetylacetone Iron(III) Salt Ferric(III) Acetylacetonate Iron(III) Acetylacetonate
  • TRIS(2,4-PENTANEDIONATO)IRON
  • TRIS(2,4-PENTANEDIONATO)IRON(3)
  • TRIS(2,4-PENTANEDIONATO)IRON(III)
  • TRIS(ACETYLACETONATO)IRON(III)
  • (Acetylacetonato)iron(iii)
  • (OC-6-11)-tris(2,4-pentanedionato-O,o’)-iron
  • 4-pentanedionato-o,o’)-tris((oc-6-11)-iro
CAS:
14024-18-1
MF:
C15H21FeO6
MW:
353.17
EINECS:
237-853-5
Product Categories:
  • metal beta-diketonate complexes
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Environmentally-friendly Oxidation
  • Fe (Iron) Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Synthetic Organic Chemistry
  • Transition Metal Complexes (Environmentally-friendly Oxidation)
  • Transition Metal Compounds
  • Organometallics
Mol File:
14024-18-1.mol
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Ferric acetylacetonate Chemical Properties

Melting point:
180-182 °C (dec.)(lit.)
Boiling point:
110°C 2mm
Density 
5.24 g/mL at 25 °C(lit.)
vapor pressure 
2.6 hPa (110 °C)
storage temp. 
Store below +30°C.
solubility 
Soluble in toluene.
form 
Powder
Specific Gravity
5.24
color 
Red
Water Solubility 
2 g/L (20 ºC)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
4157960
Stability:
Stable. Incompatible with strong bases, strong oxidizing agents.
NIST Chemistry Reference
Iron tris(acetylacetonate)(14024-18-1)
EPA Substance Registry System
Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-36
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
NO8960000
21
TSCA 
Yes
HS Code 
29420000
Toxicity
LD50 orally in Rabbit: 1872 mg/kg

MSDS

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Ferric acetylacetonate Usage And Synthesis

Chemical Properties

dark red powder

Uses

Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.

Preparation

Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.

Purification Methods

When recrystallised twice from *benzene/pet ether, it has m 181.3-182.3o corr [Finn et al. J Chem Soc 1256 1938]. However, when recrystallised from EtOH or Et2O it has m 179o [Hantzsch & Desch Justus Liebigs Ann Chem 323 13 1902]. Recrystallisation from absolute EtOH gives material with m 159.5o [Emmert & Jacob Chem Ber 67 286 1934]. Dry it for 1hour at 120o. [Beilstein 1 IV 606, 2 IV 1908.]

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