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THALLIUM (I) ETHOXIDE

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THALLIUM (I) ETHOXIDE Basic information

Product Name:
THALLIUM (I) ETHOXIDE
Synonyms:
  • ethanol,thallium(1+)salt
  • ethanol,thallium(1++)salt
  • ethylalcohol,thallium(i)
  • THALLOUS ETHOXIDE
  • THALLIUM MONOETHYLATE
  • THALLIUM ETHOXIDE
  • THALLIUM ETHYLATE (MONO)
  • THALLIUM (I) ETHOXIDE
CAS:
20398-06-5
MF:
C2H5OTl
MW:
249.44
EINECS:
243-786-2
Product Categories:
  • metal alkoxide
Mol File:
20398-06-5.mol
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THALLIUM (I) ETHOXIDE Chemical Properties

Melting point:
-3°C
Boiling point:
130°C
Density 
3.522 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.676(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Methanol (Slightly), Water (Soluble)
form 
liquid
Specific Gravity
3.493 (20℃)
color 
cloudy, dense
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 0.02 mg/m3 (Skin)
NIOSH: IDLH 15 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
20398-06-5(CAS DataBase Reference)
EPA Substance Registry System
Ethanol, thallium(1+) salt (20398-06-5)
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Safety Information

Hazard Codes 
T+,N
Risk Statements 
26/28-33-51/53
Safety Statements 
13-28-45-61
RIDADR 
UN 1707 6.1/PG 2
WGK Germany 
3
RTECS 
KM2940000
TSCA 
Yes
HazardClass 
3
PackingGroup 
II

MSDS

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THALLIUM (I) ETHOXIDE Usage And Synthesis

Chemical Properties

cloudy, dense liquid; sensitive to moisture [STR93]

Uses

Thallium Ethoxide is used as a catalyst in suzuki cross coupling reactions.

Uses

With HCl, reduces a variety of functional groups; stereoselective allylation of carbonyl compounds; in situ generation of tin enolates for directed aldol reactions.

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of T1. See also THALLIUM COMPOUNDS

THALLIUM (I) ETHOXIDESupplier

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