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THALLIUM (I) ETHOXIDE

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THALLIUM (I) ETHOXIDE Basic information

Product Name:
THALLIUM (I) ETHOXIDE
Synonyms:
  • ethanol,thallium(1+)salt
  • ethanol,thallium(1++)salt
  • ethylalcohol,thallium(i)
  • THALLOUS ETHOXIDE
  • THALLIUM MONOETHYLATE
  • THALLIUM ETHOXIDE
  • THALLIUM ETHYLATE (MONO)
  • THALLIUM (I) ETHOXIDE
CAS:
20398-06-5
MF:
C2H5OTl
MW:
249.44
EINECS:
243-786-2
Product Categories:
  • metal alkoxide
Mol File:
20398-06-5.mol
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THALLIUM (I) ETHOXIDE Chemical Properties

Melting point:
-3°C
Boiling point:
130°C
Density 
3.522 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.676(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
Methanol (Slightly), Water (Soluble)
form 
liquid
Specific Gravity
3.493 (20℃)
color 
cloudy, dense
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 0.02 mg/m3 (Skin)
NIOSH: IDLH 15 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
20398-06-5(CAS DataBase Reference)
EPA Substance Registry System
Ethanol, thallium(1+) salt (20398-06-5)
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Safety Information

Hazard Codes 
T+,N
Risk Statements 
26/28-33-51/53
Safety Statements 
13-28-45-61
RIDADR 
UN 1707 6.1/PG 2
WGK Germany 
3
RTECS 
KM2940000
TSCA 
Yes
HazardClass 
3
PackingGroup 
II

MSDS

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THALLIUM (I) ETHOXIDE Usage And Synthesis

Chemical Properties

cloudy, dense liquid; sensitive to moisture [STR93]

Uses

Thallium Ethoxide is used as a catalyst in suzuki cross coupling reactions.

Uses

With HCl, reduces a variety of functional groups; stereoselective allylation of carbonyl compounds; in situ generation of tin enolates for directed aldol reactions.

reaction suitability

core: thallium
reagent type: catalyst

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of T1. See also THALLIUM COMPOUNDS

THALLIUM (I) ETHOXIDESupplier

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