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meso-Tetra(4-carboxyphenyl)porphine

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meso-Tetra(4-carboxyphenyl)porphine Basic information

Product Name:
meso-Tetra(4-carboxyphenyl)porphine
Synonyms:
  • TETRACARBOXYPHENYLPORPHYRIN
  • TETRAKIS(4-CARBOXYPHENYL)PORPHINE
  • RARECHEM AS SA 0048
  • NICKEL IONOPHORE II
  • MESO-TETRA(4-CARBOXYPHENYL)PORPHINE
  • MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID
  • 5,10,15,20-TETRA(4-CARBOXYPHENYL)PORPHYRIN
  • 5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN
CAS:
14609-54-2
MF:
C48H30N4O8
MW:
790.77
Product Categories:
  • porphine (porphyrin) ligand
  • Porphyrins
  • Synthetic Porphyrins
  • Analytical Chemistry
  • Biochemistry
  • Chelating Reagents
  • Ligands for Pharmaceutical Research
  • Magnetic Resonance Imaging (Chelating Reagents)
  • Porphines
Mol File:
14609-54-2.mol
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meso-Tetra(4-carboxyphenyl)porphine Chemical Properties

Melting point:
>300 °C
Density 
1.462±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Powder
color 
purple
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
RTECS 
DH6488300
HS Code 
2933998090
Hazardous Substances Data
14609-54-2(Hazardous Substances Data)

MSDS

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meso-Tetra(4-carboxyphenyl)porphine Usage And Synthesis

Uses

meso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.

Uses

Nickel ionophore II is a selective sensor for Ni(II) ions.

Uses

4,4′,4′′, 4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) (H2TCPP) can be used to fabricate three dimensional Ru polymer complex. It can be grafted on SiO2/Nb2O5 substrate and subsequently metallized to investigate catalytic oxidation of hydrazine.

General Description

Visit our Sensor Applications portal to learn more.

Synthesis


General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent).

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