(S)-1-(3-BROMOPHENYL)ETHANOL Chemical Properties

Boiling point:

264℃

Density 

1.470

Flash point:

114℃

storage temp. 

2-8°C

form 

Liquid

pka

14.35±0.20(Predicted)

color 

Clear colorless

Safety Information

Hazard Codes 

Xn

Risk Statements 

36/37/38-20/21/22

Safety Statements 

36/37/39-26

HS Code 

29062900

MSDS

• Language:English Provider:ACROS

(S)-1-(3-BROMOPHENYL)ETHANOL Usage And Synthesis

Chemical Properties

clear colorless liquid

Synthesis

General procedure for the synthesis of 1-(3-bromophenyl)ethanol and (S)-1-(3-bromophenyl)ethanol from 3'-bromoacetophenone: under dry argon protection, the catalyst [0.4 mol% (complexes 12-22) or 0.2 mol% (dinuclear complex 24)] and 3'-bromoacetophenone (2.5 mmol) were added to a three necked Schlenk flask. The mixture was stirred at 82 °C for 15 min before adding 5 mL of a 0.06 M solution of base (Cs2CO3) in 2-propanol (0.3 mmol). The reaction progress was monitored by an HP-6890 gas chromatograph. In all reactions, only the corresponding alcohols and ketones were detected as products. Conversion rates and enantiomeric excess values (e.e. values) were determined by gas chromatography using a Supelco β-DEX 120 chiral capillary column.

References

[1] Molecular Catalysis, 2018, vol. 456, p. 75 - 86
[2] Tetrahedron Letters, 2018, vol. 59, # 8, p. 719 - 722
[3] Angewandte Chemie, 1995, vol. 107, # 18, p. 2165 - 2166
[4] Angewandte Chemie, 1995, vol. 107, # 18, p. 2165 - 2166
[5] Journal of Organometallic Chemistry, 1997, vol. 547, # 1, p. 97 - 101

(S)-1-(3-BROMOPHENYL)ETHANOL(134615-22-8)Related Product Information

• Acid Red 92
• 4',5'-DIBROMOFLUORESCEIN
• Bromocresol Purple
• Bromochlorophenol Blue sodium salt
• Acid Red 87
• 3',3'',5',5''-TETRABROMOPHENOLPHTHALEIN
• Tetrabromophenol Blue
• Bromophenol Blue
• 5''-BROMOSPIRO[1,3-DIOXOLANE-2,3''-INDOL]-2''(1''H)-ONE
• Bromoxylenol Blue
• 2',4',5',7'-TETRABROMO-3,4,5,6-TETRACHLOROFLUORESCEIN
• 3,4,5,6-Tetrabromophenolsulfonephthalein
• Bromocresol green
• 4,5,6,7-TETRABROMOPHENOLPHTHALEIN
• Bromophenol Red sodium salt
• BTB
• 2-(P-BROMOPHENYL)ETHANOL,2-(4-BROMOPHENYL)ETHANOL
• 2-(3-BROMOPHENYL)ETHANOL