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5-AMINOPYRIMIDINE

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5-AMINOPYRIMIDINE Basic information

Product Name:
5-AMINOPYRIMIDINE
Synonyms:
  • 5-AMINOPYRIMIDINE
  • PYRIMIDIN-5-AMINE
  • PYRIMIDIN-5-YLAMINE
  • 5-Pyrimidinamine (9CI)
  • 5-Pyrimidinamine
  • 5-AMINOPYRIMIDINE (MFCD
  • Pyrimidin-5-amine, 5-Amino-1,3-diazine
  • 5-Aminopyrimidine >
CAS:
591-55-9
MF:
C4H5N3
MW:
95.1
Product Categories:
  • Heterocycle-Pyrimidine series
  • PYRIMIDINE
  • 591-55-9
Mol File:
591-55-9.mol
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5-AMINOPYRIMIDINE Chemical Properties

Melting point:
171°C(lit.)
Boiling point:
240.7±13.0 °C(Predicted)
Density 
1.216±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
2?+-.0.10(Predicted)
form 
powder to crystal
color 
White to Light yellow
λmax
315nm(EtOH)(lit.)
InChIKey
FVLAYJRLBLHIPV-UHFFFAOYSA-N
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
22-36/37/38
Safety Statements 
26
WGK Germany 
3
HazardClass 
IRRITANT-HARMFUL
HS Code 
2933599590
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5-AMINOPYRIMIDINE Usage And Synthesis

Definition

ChEBI: Pyrimidin-5-amine is an aminopyrimidine.

Purification Methods

It is purified by conversion to the MgCl2 complex in a small volume of H2O. The complex (~ 5g) is dissolved in the minimum volume of hot H2O, passed through a column of activated Al2O3 (200g), and the column is washed with EtOH. Evaporation of the EtOH gives a colourless residue of the aminopyrimidine which is recrystallised from *C6H6 (toluene could also be used) which forms needles at first, then prisms. It melts with sublimation. Acetylation yields 5-acetamidopyrimidine which crystallises from *C6H6, m 148-149o. [Whittaker J Chem Soc 1565 1951.]

5-AMINOPYRIMIDINE Preparation Products And Raw materials

Raw materials

5-AMINOPYRIMIDINESupplier

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