ChemicalBook > Product Catalog > Biochemical Engineering > Amino Acids and Derivatives > Amino alcohol derivative > (R)-alpha,alpha-Diphenylmethylprolinol
(R)-alpha,alpha-Diphenylmethylprolinol
(R)-alpha,alpha-Diphenylmethylprolinol Basic information
- Product Name:
- (R)-alpha,alpha-Diphenylmethylprolinol
- Synonyms:
-
- (2R)-(-)-2-[Diphenyl(hydroxy)methyl]-1-methylpyrrolidine, (-)-alpha,alpha-Diphenyl-N-methyl-D-prolinol
- (2R)-N-Methyl-α,α-diphenyl-2-pyrrolidinemethanol
- (2R)-N-Methyl-α,α-diphenyl-2-pyrrolidinemethanol,99%e.e.
- (2R)-(-)-N-Methyl-α,α-diphenyl-2-pyrrolidinemethanol, min. 98%
- [(2R)-1-methylpyrrolidin-2-yl]-diphenylmethanol
- (2R)-(-)-N-Methyl-α
- -diphenyl-2-pyrrolidinemethanol, min. 98%
- α,α-Diphenyl-N-methyl-D-prolinol, 98%, ee: 98%
- CAS:
- 144119-12-0
- MF:
- C18H21NO
- MW:
- 267.37
- EINECS:
- 635-081-7
- Product Categories:
-
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- Mol File:
- 144119-12-0.mol
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(R)-alpha,alpha-Diphenylmethylprolinol Chemical Properties
- Melting point:
- 68-71 °C
- alpha
- -52° (c=1, CHCl3)
- Boiling point:
- 406.8±25.0 °C(Predicted)
- Density
- 1.116±0.06 g/cm3(Predicted)
- refractive index
- -55 ° (C=1, CHCl3)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Powder
- pka
- 13.15±0.29(Predicted)
- color
- white to light-yellow
- optical activity
- [α]20/D 55.0±4.0°, c = 1% in chloroform stab. with amylenes
- BRN
- 1535407
- CAS DataBase Reference
- 144119-12-0(CAS DataBase Reference)
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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(R)-alpha,alpha-Diphenylmethylprolinol Usage And Synthesis
Reaction
- Chiral amino alcohol assisted asymmetric, enantioselective, aryl transfer of triphenylboroxin to a set of aryl aldehydes in the presence of chiral amino alcohols derived from (S)-proline.
- Pyrrolidinylmethanol compound used for the zinc-catalyzed addition of arylboronic acids to aromatic aldehydes, proceeding in high yields and high enantioselectivities (up to 98% ee).
Chemical Properties
white to off-white crystalline powder
(R)-alpha,alpha-DiphenylmethylprolinolSupplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
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Alfa Aesar
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- 400-6106006
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
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Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
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(R)-alpha,alpha-Diphenylmethylprolinol(144119-12-0)Related Product Information
- D(-)Prolinol
- Methanol
- (S)-ALPHA,ALPHA-DIPHENYLMETHYLPROLINOL
- N-Methyl-L-prolinol
- (R)-2-AMINO-1,2-DIPHENYL-1-PROPANOL
- (+)-N-METHYLEPHEDRINE
- (-)-Pseudoephedrine
- (R)-(+)-a,a-Diphenyl-2-pyrrolidinemethanol
- (R)-alpha,alpha-Diphenylmethylprolinol
- (S)-2-Dimethylamino-1-phenyletanol
- N-Methyl-D-prolinol
- 2-BENZYLPYRROLIDINE
- (R)-1,1-DIPHENYL-2-AMINOPROPANE
- (R)-(+)-2-(DIPHENYLMETHYL)PYRROLIDINE
- (R,R)-(-)-2,6-BIS[2-(HYDROXYDIPHENYLMETHYL)-1-PYRROLIDINYL-METHYL]-4-METHYLPHENOL
- (R*,R*)-alpha-(1-aminoethyl)benzyl alcohol
- N-Methyl-DL-prolinol
- (1R,2R)-(-)-N-METHYLPSEUDOEPHEDRINE