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1,6-Dibromopyrene

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1,6-Dibromopyrene Basic information

Product Name:
1,6-Dibromopyrene
Synonyms:
  • 6-DibroMopyrene
  • Pyrene, 1,6-dibromo-
  • 1,6-Dibromopyrene
  • 1,6-dlbrornopyrone
  • 1,6-Dibromopyrene>
  • 1,6-Dibromopyrene ISO 9001:2015 REACH
CAS:
27973-29-1
MF:
C16H8Br2
MW:
360.04
EINECS:
1308068-626-2
Product Categories:
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis
  • intermediate
  • OLED
  • OLED materrials
Mol File:
27973-29-1.mol
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1,6-Dibromopyrene Chemical Properties

Melting point:
228.0 to 232.0 °C
Boiling point:
469.6±18.0 °C(Predicted)
Density 
1.852±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Very Slightly, Heated), Methanol (Very Slightly, Heated)
form 
Solid
color 
White to Off-White
λmax
246nm(EtOH)(lit.)
InChI
InChI=1S/C16H8Br2/c17-13-8-4-10-2-6-12-14(18)7-3-9-1-5-11(13)16(10)15(9)12/h1-8H
InChIKey
JRCJYPMNBNNCFE-UHFFFAOYSA-N
SMILES
C1(Br)=C2C3=C4C(C=C2)=CC=C(Br)C4=CC=C3C=C1
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
29039990
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1,6-Dibromopyrene Usage And Synthesis

Description

1, 6-dibromopyrene is a kind of pyrene chemical. It is majorly used as organic intermediate, OLED (organic light-emitting diodes) materials and photoelectric material. It, together with its 1, 8- isomer, can be produced by the double bromination of pyrene with bromine. It can be applied to the synthesis of bipyridine and terpyridine based ruthenium metallosynthons.

Chemical Properties

white powder

References

Goze, Christine, et al. "Synthesis of bipyridine and terpyridine based ruthenium metallosynthons for grafting of multiple pyrene auxiliaries."Tetrahedron letters 44.48 (2003): 8713-8716.
Kaplunov, Mikhail G., et al. "Novel 1, 8-bis(diarylamino)pyrenes as OLED materials." Mendeleev Communications 26.5(2016):437-439.
Gong, Xiaojie, et al. "Two Symmetrically Bis‐substituted Pyrene Derivatives: Synthesis, Photoluminescence, and Electroluminescence." Chinese Journal of Chemistry 33.8 (2015): 967-973.

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