ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic palladium > Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Basic information
- Product Name:
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- Synonyms:
-
- Pd(aMphos)Cl2, 15% Pd, Product of UMicore
- Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…
- Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)-
- palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride
- Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride 95+%
- Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride
- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos
- Pd132
- CAS:
- 887919-35-9
- MF:
- C32H58Cl2N2P2Pd
- MW:
- 710.1
- EINECS:
- 627-800-8
- Product Categories:
-
- Pd
- Mol File:
- 887919-35-9.mol
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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- Powder
- color
- yellow
- Water Solubility
- Insoluble in water.
- InChI
- InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
- InChIKey
- AWOFSUFKCXRJMV-UHFFFAOYSA-N
- SMILES
- P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C
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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Usage And Synthesis
Reaction
- Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
- Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.
Chemical Properties
Yellow powder
Uses
Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.
Uses
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
Synthesis
To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)Supplier
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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)(887919-35-9)Related Product Information
- DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
- (R)-(-)-1-[(S)-2-(DI(3,5-BIS-TRIFLUOROMETHYLPHENYL)PHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
- (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97%
- (R)-(+)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
- DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
- DICHLOROBIS(INDENYL)TITANIUM(IV)
- Ruthenium(II) chloride mesitylene dimer
- Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
- BrettPhos Pd G4
- XPhos Pd G2
- SPhos Pd G2
- Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), min. 98%
- DI-TERT-BUTYLPHENYLPHOSPHINE
- Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
- dichlorobis(di-tert-butylphenylphosphine)palladium(II)
- Bis(di-tert-butyl)-4-dimethylaminophenylphosphine