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1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride

Basic information Safety Supplier Related

1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride Basic information

Product Name:
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride
Synonyms:
  • Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)
  • Dichloro(1,3-dimesityl-2-imidazolidinylidene)[5-(dimethylsulfamoyl)-2-isopropoxybenzylidene]ruthenium
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride
  • RUTHENIUM, [1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-[[2-ISOPROPOXY-5-(N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENE]
  • ZHAN CATALYST-1B
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,
    N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride Zhan Catalyst-1B
  • 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-4,5-DIHYDROIMIDAZOL-2-YLIDENE[2-(I-PROPOXY)-5-(N,N-DIMETHYLAMINOSULFONYL)PHENYL]METHYLENERUTHENIUM(II)DICHLORIDE,ZHANCATALYST-1B,MIN96%
  • 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium (II) dichloride, Zhan Catalyst-1B, min 96%
CAS:
918870-76-5
MF:
C33H42Cl2N3O3RuS
MW:
732.75
Product Categories:
  • organometallic complex
Mol File:
918870-76-5.mol
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1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride Chemical Properties

form 
solid
color 
green
InChI
InChI=1S/C21H26N2.C12H16NO3S.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-9(2)16-12-7-6-11(8-10(12)3)17(14,15)13(4)5;;;/h9-12H,7-8H2,1-6H3;6-9H,1-2,4-5H3;2*1H;/q2*-2;;;+6/p-2
InChIKey
JIZPWEVWTYCVNK-UHFFFAOYSA-L
SMILES
[Cl-][Ru+6]1(=[C-2]C2=CC(S(=O)(=O)N(C)C)=CC=C2O1C(C)C)(=[C-2]1N(C2C(=CC(C)=CC=2C)C)CCN1C1C(=CC(C)=CC=1C)C)[Cl-]
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride Usage And Synthesis

Uses

Zhan Catalyst-1B (Hoveyda-Grubbs type catalyst) can be used:

  • In the preparation of hybrid olefin metathesis catalysts, with increased catalytic activity via immobilization on molecular seives. supports
  • As a catalyst in the synthesis of divergent dendrimer
  • In ring-closure metathesis (RCM) reaction.

1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichlorideSupplier

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