2-Bromo-3-methylpyridine Chemical Properties

Boiling point:

218-219 °C (lit.)

Density 

1.544 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.568(lit.)

Flash point:

>230 °F

storage temp. 

Inert atmosphere,Room Temperature

pka

1.08±0.10(Predicted)

form 

Liquid

Specific Gravity

1.55

color 

Clear slightly yellow to light brown

BRN 

107896

InChI

InChI=1S/C6H6BrN/c1-5-3-2-4-8-6(5)7/h2-4H,1H3

InChIKey

PZSISEFPCYMBDL-UHFFFAOYSA-N

SMILES

C1(Br)=NC=CC=C1C

CAS DataBase Reference

3430-17-9(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-37/39-36/37/39-36

WGK Germany 

3

Hazard Note 

Harmful

HazardClass 

IRRITANT

PackingGroup 

III

HS Code 

29333990

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

2-Bromo-3-methylpyridine Usage And Synthesis

Chemical Properties

clear slightly yellow to light brown liquid

Synthesis

A solution of 2,3-dibromopyridine (0.10 M, 3.0 mL) in THF was stirred at T ℃. A solution of n-BuLi (0.40 M, 0.75 mL) in hexane was added dropwise to this solution at a regular pace for 1.0 min. After stirring for 10 min, iodomethane (0.60 M, 1.5 mL) was added dropwise to this mixture at a regular pace for 1.0 min. After stirring at T ℃ for 10 min, a cooling bath was removed. When the reaction mixture reached room temperature and was quenched with H2O, the yields of 2-bromo-3-methylpyridine (2) and 2-bromopyridine (3) and the conversion of 2,3-dibromopyridine (1) was analyzed by GC.

2-Bromo-3-methylpyridine(3430-17-9)Related Product Information

• 5-AMINO-2-BROMO-3-METHYLPYRIDINE
• 2-BROMO-4-METHYLPYRIDINE
• 3-AMINO-2-BROMO-5-PICOLINE
• 2-(Vinyloxy)ethanol
• 2-Bromo-3-methyl-5-nitropyridine
• 2-Bromo-3-methyl-5-chloropyridine
• 2-Bromo-3-trifluoromethylpyridine
• 2-Bromo-3-methylbenzaldehyde
• 2-Bromo-4-nitroimidazole
• 2-Bromo-4-fluoropyridine
• 2-Bromo-5,6-diphenylpyrazine
• 2-Bromo-4-chloropyridine
• 2-Bromo-3-fluoropyridine
• 3-Amino-2-bromopyridine
• 2-Bromopyridine-4-carboxylic acid
• BenzenaMine, 2-broMo-5-fluoro-4-nitro-
• 2-Bromo-3,5-dichloropyridine
• Pyridine, 2-bromo-3,5-dichloro-6-methyl-