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4-CHLOROTETRAHYDROPYRAN

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4-CHLOROTETRAHYDROPYRAN Basic information

Product Name:
4-CHLOROTETRAHYDROPYRAN
Synonyms:
  • 4-Chlorotetrahydro-2H-pyran
  • 4-CHLOROTETRAHYDROPYRAN
  • 4-chlorooxane
  • 4-chlorotetrahydro-2H-pyran(SALTDATA: FREE)
  • Tetrahydro-2H-pyran-4-chloride
  • 4-Chlorotetrapyran
  • 4-chlorotetrahydro-2H-pran-4-one
  • 4-Chlorotetrahydropyran 96%
CAS:
1768-64-5
MF:
C5H9ClO
MW:
120.58
Product Categories:
  • Heterocycle-other series
Mol File:
1768-64-5.mol
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4-CHLOROTETRAHYDROPYRAN Chemical Properties

Boiling point:
150 °C(lit.)
Density 
1.114 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.462(lit.)
Flash point:
114 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
water: soluble(lit.)
form 
Liquid
color 
Colorless to dark yellow
Stability:
Volatile
InChIKey
DHRSKOBIDIDMJZ-UHFFFAOYSA-N
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
16-26-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
HazardClass 
3.2
PackingGroup 
III
HS Code 
2932990090

MSDS

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4-CHLOROTETRAHYDROPYRAN Usage And Synthesis

Chemical Properties

Colorless to pale yellow liquid

Uses

4-Chlorotetrahydropyran is a useful reagent for the synthetic preparation of coupling products via iridium photo-catalyzed cross-electrophile coupling.

Uses

4-Chlorotetrahydropyran was used in the synthesis of 3-chlorogutaric acid.

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 2748, 1989 DOI: 10.1021/jo00272a055
Tetrahedron Letters, 25, p. 2653, 1984 DOI: 10.1016/S0040-4039(01)81254-5

General Description

4-Chlorotetrahydropyran is a commonly employed starting material in organic synthesis.

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