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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE

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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Basic information

Product Name:
(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
Synonyms:
  • CARBETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE
  • (CARBOETHOXYMETHYL)-TRIPHENYLPHOSPHONIUMCHLORID
  • (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
  • (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
  • (ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE
  • (4-ETHOXYCARBONYL)TRIPHENYLPHOSPHONIUM CHLORIDE
  • (2-ethoxy-2-oxoethyl)triphenylphosphonium chloride
  • (ETHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONI UM CHLORIDE, TECH., 80%
CAS:
17577-28-5
MF:
C22H22O2P.Cl
MW:
384.84
EINECS:
241-548-2
Mol File:
17577-28-5.mol
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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Chemical Properties

Melting point:
120-123 °C (dec.) 120-123 °C (lit.)
storage temp. 
2-8°C
Sensitive 
Hygroscopic
BRN 
3924139
CAS DataBase Reference
17577-28-5(CAS DataBase Reference)
EPA Substance Registry System
Phosphonium, (2-ethoxy-2-oxoethyl)triphenyl-, chloride (17577-28-5)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
9
TSCA 
Yes
HS Code 
29319019

MSDS

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(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE Usage And Synthesis

Chemical Properties

white to off-white crystals or crystalline powder

Uses

Reactant for:

  • Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
  • Ring-opening reactions with Wittig reagents
  • Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
  • Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
  • Preparation of phosphonium derivatives of coumarin

(CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATESupplier

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