6-Methylquinoline
6-Methylquinoline Basic information
- Product Name:
- 6-Methylquinoline
- Synonyms:
-
- 6-methyl-quinolin
- p-Methylquinoline
- FEMA 2744
- 6-METHYLQUINOLINE
- P-TOLUQUINOLINE
- PARA METHYL QUINOLINE
- 6-METHYLQUINOLINE 98+%
- Quinoline, 6-methyl-
- CAS:
- 91-62-3
- MF:
- C10H9N
- MW:
- 143.19
- EINECS:
- 202-084-6
- Product Categories:
-
- Alkylquinolines
- FluoroCompounds
- blocks
- Quinolines
- Quinoline&Isoquinoline
- Quinoline Derivertives
- Mol File:
- 91-62-3.mol
6-Methylquinoline Chemical Properties
- Melting point:
- -22°C
- Boiling point:
- 256-260 °C (lit.)
- Density
- 1.067 g/mL at 20 °C (lit.)
- vapor density
- >1 (vs air)
- refractive index
- n20/D 1.614(lit.)
- FEMA
- 2744 | 6-METHYLQUINOLINE
- Flash point:
- >230 °F
- storage temp.
- Store below +30°C.
- solubility
- Chloroform (Slightly), Methanol (Slightly), soluble in alcohol and oils, and in Propylene glycol.
- form
- Liquid
- pka
- 5.21±0.10(Predicted)
- color
- green-yellow
- Specific Gravity
- 1.07
- Odor
- blossom odor, sweet, animalic upon dilution
- Odor Type
- animal
- Water Solubility
- Not miscible or difficult to mix with water.
- Sensitive
- Light Sensitive
- JECFA Number
- 1302
- BRN
- 110336
- LogP
- 2.54
- CAS DataBase Reference
- 91-62-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Quinoline, 6-methyl-(91-62-3)
- EPA Substance Registry System
- 6-Methylquinoline (91-62-3)
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 22-38-68-36/37/38
- Safety Statements
- 26-36-45-36/37/39
- WGK Germany
- 3
- RTECS
- VC0550000
- TSCA
- Yes
- HS Code
- 29334990
MSDS
- Language:English Provider:6-Methylquinoline
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
6-Methylquinoline Usage And Synthesis
Chemical Properties
6-Methylquinoline is a clear light yellow to light orange liquid that has a pungent, heavy odor. dissolved in 4 volumes of 50% ethanol or 60% ethanol of the same volume and in oily fragrances. May be synthesized from p-amino-benzaldehyde and acetone.
Occurrence
Reported found in Finnish and Japanese whiskey.
Application
6-Methylquinoline, is a building block used for the synthesis of various pharmaceutical compounds, and biologically active compounds. It can be used for the preparation of pyranobenzopyrone compounds, having anti-norovirus activity.
Uses
6-Methylquinoline can be used as primary carbon source in culture of Pseudomonas putida QP1. 6-Methylquinoline was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and fluorescent probes for determination of chloride in biological systems.
Definition
ChEBI: 6-methylquinoline is a member of quinolines.
General Description
Clear pale yellow liquid or oil with a quinoline odor.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
6-Methylquinoline is sensitive to prolonged exposure to light. May react vigorously with strong oxidizing agents and strong acids . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire Hazard
6-Methylquinoline is probably combustible.
Biochem/physiol Actions
6-Methylquinoline undergoes biodegradation by quinoline-degrading culture of Pseudomonas putida.
Synthesis
6-Methylquinoline is obtain from coal tar, by synthesis from p-aminobenzaldehyde and acetone.
Purification Methods
Reflux it with BaO, then fractionally distil it. Further purified it via its recrystallised ZnCl2 complex (m 190o). [Cumper et al. J Chem Soc 1176 1962, Beilstein 20 III/IV 3498, 20/7 V 400.]
6-Methylquinoline Preparation Products And Raw materials
Preparation Products
6-MethylquinolineSupplier
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6-Methylquinoline(91-62-3)Related Product Information
- Ethoxyquin
- Quinolinic acid
- 6-Hydroxy-2(1H)-3,4-dihydroquinolinone
- 8-Methylquinoline
- Isoquinoline
- Quinclorac
- Quinhydrone
- 1,2,3,4-TETRAHYDROISOQUINOLINE
- 6-METHOXY-8-NITROQUINOLINE
- 4-METHYLQUINOLINE
- 5,6-Dimethyl-1,10-phenanthroline
- CI 46025
- 6-ISOPROPYLQUINOLINE
- FLAVANTHRONE
- 5-METHYL-1,10-PHENANTHROLINE
- 1,3-Dichloro-7-methylisoquinoline
- 2,6-DIMETHYLQUINOLINE
- CI NO 46040