Basic information Uses Safety Supplier Related

1-BUTANOL,3-METHYL-,PHOSPHATE

Basic information Uses Safety Supplier Related

1-BUTANOL,3-METHYL-,PHOSPHATE Basic information

Product Name:
1-BUTANOL,3-METHYL-,PHOSPHATE
Synonyms:
  • 1-BUTANOL,3-METHYL-,PHOSPHATE
  • Phosphoric acid triisoamyl ester
  • Phosphoric acid tris(3-methylbutyl) ester
  • tri(3-methyl-1-butyl) phosphate
  • 1-Butanol, 3-methyl-, 1,1',1''-phosphate
  • TIAP
  • Triisopentylphosphat
  • triisoamyl phosphate
CAS:
919-62-0
MF:
C15H33O4P
MW:
308.39
Mol File:
919-62-0.mol
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1-BUTANOL,3-METHYL-,PHOSPHATE Chemical Properties

Boiling point:
297.7±8.0 °C(Predicted)
Density 
0.962±0.06 g/cm3(Predicted)
InChI
InChI=1S/C15H33O4P/c1-13(2)7-10-17-20(16,18-11-8-14(3)4)19-12-9-15(5)6/h13-15H,7-12H2,1-6H3
InChIKey
YQLIHRFKJJQBAF-UHFFFAOYSA-N
SMILES
P(OCCC(C)C)(OCCC(C)C)(OCCC(C)C)=O
EPA Substance Registry System
1-Butanol, 3-methyl-, phosphate (3:1) (919-62-0)
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1-BUTANOL,3-METHYL-,PHOSPHATE Usage And Synthesis

Uses

Triisoamyl phosphate (TiAP) is considered an excellent extractant for the extraction and separation of actinide elements due to its superior physicochemical properties, and is particularly suitable for systems with high irradiation doses and systems with high relative plutonium concentrations.

Purification Methods

Purify the ester by repeated crystallisation, from hexane, of its addition compound with uranyl nitrate. Decompose the complex, and distil the ester at high vacuum. [Siddall J Am Chem Soc 81 4176 1959.] [see tributyl phosphate and Cherbuliez in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973.]

1-BUTANOL,3-METHYL-,PHOSPHATESupplier

Zhangjiagang Xinya Chemical Co., Ltd. Gold
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