Bis(triphenylphosphine)nickel(II) bromide Chemical Properties

Melting point:

219-223 °C (lit.)

storage temp. 

Inert atmosphere,Room Temperature

form 

crystal

color 

green

Exposure limits

NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3

InChI

InChI=1S/2C18H15P.2BrH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey

QEKXARSPUFVXIX-UHFFFAOYSA-L

SMILES

P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Br)Br

CAS DataBase Reference

14126-37-5(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22

Safety Statements 

36/37

RIDADR 

UN 1759 8/PG 2

WGK Germany 

3

HazardClass 

6.1(b)

PackingGroup 

III

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Bis(triphenylphosphine)nickel(II) bromide Usage And Synthesis

Chemical Properties

DARK GREEN CRYSTALLINE POWDER OR CRYSTALS

Uses

As a polymerization catalyst

Uses

Catalysts for the cross-coupling reactions, C-X bond reduction, homocoupling of Csp2 halides, displacement of aryl halides, and oligomerization of dienes

Bis(triphenylphosphine)nickel(II) bromide(14126-37-5)Related Product Information

• Titanous chloride
• NICKEL OXALATE DIHYDRATE
• Benzophenone
• 1,2-Dimethoxyethane
• BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
• Bis-(triphenylphosphino)-cuprous borohydride
• DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
• BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
• Bis(triphenylphosphinepalladium) acetate
• Bis(dibenzylideneacetone)palladium
• Bis(cyclopentadienyl)zirconium dichloride
• BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE
• Bis[Tris(2-methylphenyl)phosphine]palladium
• DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
• BIS(DI-TERT-BUTYLPHOSPHINO)METHANE
• dichlorobis(di-tert-butylphenylphosphine)palladium(II)
• Titanocene dichloride
• Bis(tricyclohexylphosphine)palladium(II) Dichloride