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DIchloro[bis(diphenylphosphinophenyl)ether]palladium(II)

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DIchloro[bis(diphenylphosphinophenyl)ether]palladium(II) Basic information

Product Name:
DIchloro[bis(diphenylphosphinophenyl)ether]palladium(II)
Synonyms:
  • Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II)
  • bis(diphenylphosphinophenyl)etherpalladium(II)...
  • Bis(diphenylphosphinophenyl)ether palladium (II) dichloride
  • Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II), Pd 14.8%
  • Dichloro[bis(2-(diphenylphosphino)phenyl)ether]palladium(II)
  • Pd-117
  • cis-[Bis[2-(diphenylphosphino)phenyl] ether]dichloropalladium
  • DICHLORO{BIS[2-(DIPHENYLPHOSPHINO)PHENYL]ETHER}PALLADIUM(II),98%
CAS:
205319-06-8
MF:
C36H28Cl2OP2Pd
MW:
717.9
Mol File:
205319-06-8.mol
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DIchloro[bis(diphenylphosphinophenyl)ether]palladium(II) Chemical Properties

Melting point:
243-250°C
storage temp. 
2-8°C
form 
Powder
color 
yellow
Water Solubility 
Insoluble in water.
InChIKey
VYOUBMJFTDMKRR-UHFFFAOYSA-L
SMILES
P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1OC1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-37
WGK Germany 
3
TSCA 
No
HS Code 
2843909000
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DIchloro[bis(diphenylphosphinophenyl)ether]palladium(II) Usage And Synthesis

Reaction

  1. Stereoretentive palladium-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
  2. Highly selective reactions of unbiased alkenyl halides: Negishi-Plus couplings.

Chemical Properties

light yellow powder

Uses

Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) is used as a catalyst for cross-coupling reaction of 2-brom-1,3-dienes to prepare high stereoselectivity of conjugated Z,E dienes.

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