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1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane

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1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane Basic information

Product Name:
1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane
Synonyms:
  • 1,1,3,3-tetramethyl-1,3-bis-(3-oxiranylmethoxy-propyl)-disiloxane
  • 1,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-disiloxan
  • 1,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-Disiloxane
  • [dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silyl]oxy-dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silane
  • 1,3-Di(3-glycidoxypropyl)-1,1,3,3-tetramethyldisiloxane
  • NSC 93976
  • 1,3-Bis(3-glycidoxypropyl)-1,1,3,3-tetraMethyldi
  • 1,3-BIS(3-(2,3-EPOXYPROPOXY)PROPYL)TETRAMETHYLDISILOXANE
CAS:
126-80-7
MF:
C16H34O5Si2
MW:
362.61
EINECS:
204-803-9
Product Categories:
  • Chemical Synthesis
  • Organometallic Reagents
  • Organosilicon
  • Siloxanes
Mol File:
126-80-7.mol
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1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane Chemical Properties

Melting point:
<0°C
Boiling point:
184 °C2 mm Hg(lit.)
Density 
0.996 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.452
Flash point:
110°C
Specific Gravity
0.996
Hydrolytic Sensitivity
3: reacts with aqueous base
BRN 
223966
InChI
InChI=1S/C16H34O5Si2/c1-22(2,9-5-7-17-11-15-13-19-15)21-23(3,4)10-6-8-18-12-16-14-20-16/h15-16H,5-14H2,1-4H3
InChIKey
MFIBZDZRPYQXOM-UHFFFAOYSA-N
SMILES
[Si](C)(C)(CCCOCC1CO1)O[Si](C)(C)CCCOCC1CO1
EPA Substance Registry System
1,1,3,3-Tetramethyl-1,3-bis[3-glycidyloxypropyl]disiloxane (126-80-7)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-21
TSCA 
Yes

MSDS

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1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane Usage And Synthesis

Uses

1,3-Bis(3-glycidyloxypropyl)tetramethyldisiloxane can be used:

  • As a starting material to synthesize functional poly(siloxane amine)s via an amine-epoxy click polymerization for material and biological applications.
  • To prepare polymer electrolyte membranes (PEM) for fuel cell applications.

Synthesis

1,1,3,3-Tetramethyldisiloxane and 1.1 equiv of allyl glycidyl ether (calculated to each Si-H group) were placed into the reaction vessel and heated up to 90 °C. Then the appropriate amount of [{Rh(OSiMe3)cod}2] (in the ratio 10-5 mol per mol Si-H) was added as a catalyst, and the reaction was continued for the next 2 h to give a crude product 1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane.

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