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α,α-Difluorophenylacetic acid

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α,α-Difluorophenylacetic acid Basic information

Product Name:
α,α-Difluorophenylacetic acid
Synonyms:
  • DIFLUORO(PHENYL)ACETIC ACID
  • 2,2-DIFLUORO-2-PHENYLACETIC ACID
  • A,A-DIFLUOROPHENYLACETIC ACID
  • ALPHA,ALPHA-DIFLUOROPHENYLACETIC ACID
  • alpha-Difluoro-benzeneacetic acid
  • ɑ,ɑ-Difluorophenylacetic acid, 99%
  • 2,3-DIFLUOROPHENYLACETIC ACID 95+%
  • 2,3-DIFLUUOROPHENYL ACETIC ACID
CAS:
360-03-2
MF:
C8H6F2O2
MW:
172.13
EINECS:
623-610-4
Product Categories:
  • Fluorinated Building Blocks
  • Organic Building Blocks
  • Aryl Fluorinated Building Blocks
  • Building Blocks
  • Organic Fluorinated Building Blocks
  • Other Fluorinated Organic Building Blocks
  • Aromatic compound
  • Fluorobenzene
  • Miscellaneous
  • C8
  • C8-C12
  • Carbonyl Compounds
  • Carboxylic Acids
  • Chemical Synthesis
Mol File:
360-03-2.mol
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α,α-Difluorophenylacetic acid Chemical Properties

Melting point:
65-75 °C
Boiling point:
0°C
Density 
1.338±0.06 g/cm3(Predicted)
Flash point:
0°C
storage temp. 
Refrigerator, Under inert atmosphere
solubility 
Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly)
form 
Solid
pka
1.04±0.10(Predicted)
color 
White to Pale Yellow
CAS DataBase Reference
360-03-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C,Xi,Xn
Risk Statements 
36/37/38
Safety Statements 
26-36-36/37-36/37/39
RIDADR 
UN3261
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
2916399090
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α,α-Difluorophenylacetic acid Usage And Synthesis

Description

α,α-Difluorophenylacetic acid is a phenylacetic acid with two fluorides on the benzylic carbon. The inductive effect of the difluoromethyl group increases the acidity of α,α-difluorophenylacetic acid. α,α-difluorophenylacetic acid and 2-arylbenzoimidazoles could be used as reaction substrates to synthesise difluoroarymethyl-substituted benzimidazo[2,1-a]isoquinolin-6(5H)-ones through radical cascade cyclization[1].

Chemical Properties

white to light yellow crystal powde

References

[1] Kaixia Sui, Yuting Leng* and Yangjie Wu*. “Synthesis of Difluoroarymethyl-Substituted Benzimidazo[2,1-a]isoquinolin-6(5H)-ones under Mild Conditions.” ACS Omega 8 8 (2023): 7517–7528.

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