ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphorus-containing compound > TRIPHENYLPHOSPHINE RESIN
TRIPHENYLPHOSPHINE RESIN
TRIPHENYLPHOSPHINE RESIN Basic information
- Product Name:
- TRIPHENYLPHOSPHINE RESIN
- Synonyms:
-
- TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G
- TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G
- TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G
- Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh
- Triphenylphosphine resin, 1% crosslinked with DVB
- 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN
- COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED
- DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN
- CAS:
- 39319-11-4
- MF:
- C18H15P
- MW:
- 262.285461
- Product Categories:
-
- Combinatorial Chemistry
- Mitsunobu Reaction
- Phosphines (Mitsunobu Reaction)
- Polymer-Supported Reagents
- Resins
- Synthetic Organic Chemistry
- Ligand
- Mol File:
- 39319-11-4.mol
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TRIPHENYLPHOSPHINE RESIN Chemical Properties
- storage temp.
- 2-8°C
- form
- Beads
- color
- White to yellow
- Sensitive
- Air Sensitive
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Safety Information
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-43-20/21/22-36/37/38
- Safety Statements
- 36/37-36-26
- WGK Germany
- 3
- F
- 10-23
- HS Code
- 29310099
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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TRIPHENYLPHOSPHINE RESIN Usage And Synthesis
Chemical Properties
white to yellow beads
Uses
Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:
- For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
- To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
- To isomerize (Z)-nitro olefins to the (E)-isomers.
- To prepare polymer-bound ylides which are useful in Wittig reactions.
- To convert alcohols or carboxylic acids to the corresponding chlorides.
- In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.
Uses
Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.
TRIPHENYLPHOSPHINE RESINSupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Capot Chemical Co., Ltd
- Tel
- +86 (0) 571 85 58 67 18
- sales@capotchem.com
Beijing Ouhe Technology Co., Ltd
- Tel
- 010-82967028 13552068683
- 2355560935@qq.com
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TRIPHENYLPHOSPHINE RESIN(39319-11-4)Related Product Information
- METHYL ISOCYANOACETATE
- Tris(2,4-pentanedionato)chroMiuM(III)
- Tosylmethyl isocyanide
- TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
- N-BUTYLISOCYANIDE
- DICHLORO(ETHYLENEDIAMINE)PLATINUM(II)
- TERT-BUTYL ISOCYANIDE
- TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)
- PHENYLSELENOL
- 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE
- 2,4-PENTANEDIONE, SILVER DERIVATIVE
- COBALT(II) ACETYLACETONATE
- Benzyl isocyanide
- SALCOMINE
- Ferric acetylacetonate
- Ethyl isocyanoacetate
- Cupric acetylacetonate
- TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G