TRIPHENYLPHOSPHINE RESIN Chemical Properties

storage temp. 

2-8°C

form 

Beads

color 

White to yellow

Sensitive 

Air Sensitive

Safety Information

Hazard Codes 

Xn,Xi

Risk Statements 

22-43-20/21/22-36/37/38

Safety Statements 

36/37-36-26

WGK Germany 

3

F 

10-23

HS Code 

29310099

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

TRIPHENYLPHOSPHINE RESIN Usage And Synthesis

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

• For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
• To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
• To isomerize (Z)-nitro olefins to the (E)-isomers.
• To prepare polymer-bound ylides which are useful in Wittig reactions.
• To convert alcohols or carboxylic acids to the corresponding chlorides.
• In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand

TRIPHENYLPHOSPHINE RESIN(39319-11-4)Related Product Information

• METHYL ISOCYANOACETATE
• Tris(2,4-pentanedionato)chroMiuM(III)
• Tosylmethyl isocyanide
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
• N-BUTYLISOCYANIDE
• DICHLORO(ETHYLENEDIAMINE)PLATINUM(II)
• TERT-BUTYL ISOCYANIDE
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)
• PHENYLSELENOL
• 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE
• 2,4-PENTANEDIONE, SILVER DERIVATIVE
• COBALT(II) ACETYLACETONATE
• Benzyl isocyanide
• SALCOMINE
• Ferric acetylacetonate
• Ethyl isocyanoacetate
• Cupric acetylacetonate
• TRIPHENYLPHOSPHINE RESIN, 1% DVB; 100-200 MESH; 1-1.5 MMOL/G