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(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

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(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Basic information

Product Name:
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
Synonyms:
  • 1,3-DIOXOLANE-4-CARBOXALDEHYDE, 2,2-DIMETHYL-, (R)-
  • (R)-2,2-DIMETHYL-[1,3]DIOXOLANE-4-CARBALDEHYDE
  • (R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXALDEHYDE
  • (R)-2,3-ISOPROPYLIDENE GLYCERALDEHYDE
  • 2,3-O-ISOPROPYLIDENE-D-GLYCERALDEHYDE
  • 2,3-O-(R)-ISOPROPYLIDENE-L-GLYCERALDEHYDE
  • (4R)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBALDEHYDE
  • D-(R)-GLYCERALDEHYDE ACETONIDE
CAS:
15186-48-8
MF:
C6H10O3
MW:
130.14
EINECS:
676-289-8
Product Categories:
  • Asymmetric Synthesis
  • Building Blocks
  • C1 to C6
  • Carbonyl Compounds
  • Chemical Synthesis
  • Chiral Building Blocks
  • pharmacetical
  • chiral
  • Chiral Reagents
  • Aldehydes
  • Chiral Building Blocks
  • Organic Building Blocks
  • Heterocyclic Building Blocks
  • Organic Building Blocks
  • API intermediates
  • Heterocycles
Mol File:
15186-48-8.mol
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(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Chemical Properties

Boiling point:
139 °C (lit.)
alpha 
53.8 º (c=2, CHCl3)
Density 
1.045 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.454(lit.)
Flash point:
143 °F
storage temp. 
-20°C
solubility 
Difficult to mix.
form 
Liquid
color 
Colorless to Pale Yellow
optical activity
[α]22/D +53.8°, c = 2 in chloroform
CAS DataBase Reference
15186-48-8(CAS DataBase Reference)
NIST Chemistry Reference
Acetone D-glyceraldehyde(15186-48-8)
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Safety Information

WGK Germany 
3
HazardClass 
6.1
HS Code 
29329990

MSDS

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(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Usage And Synthesis

Chemical Properties

Colorless Transparent Liquid

Uses

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde_x000D__x000D_Discontinued, Unstable (cas# 15186-48-8) is a compound useful in organic synthesis.

Uses

Reactant involved in organic reactions including:

  • Henry condensation reactions
  • Synthesis of highly functionalized chiral aziridines
  • Olefination of aldehydes
  • C-H oxidations
  • Aldol-type condensations
  • Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents
  • Hosomi-Sakurai reactions

Uses

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde is a reactant involved in organic reactions including:• ;Henry condensation reactions1• ;Synthesis of highly functionalized chiral aziridines2• ;Olefination of aldehydes3• ;C-H oxidations4• ;Aldol-type condensations5• ;Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents6• ;Hosomi-Sakurai reactions7

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