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2-Naphthylamine-5,7-disulfonic acid

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2-Naphthylamine-5,7-disulfonic acid Basic information

Product Name:
2-Naphthylamine-5,7-disulfonic acid
Synonyms:
  • 2-naftylamin-5,7-disulfonansodny
  • 2-Naphthylamine-5,7-disulfonicaacid
  • 6-amino-1,3-naphthalenedisulfonic
  • 6-amino-3-naphthalenedisulfonicacid
  • 6-aminonaphthalene-1,3-disulphonicacid
  • 6-amino-naphthalene-3-disulfonicacid
  • amino-iacid
  • kyselinaamino-i
CAS:
118-33-2
MF:
C10H9NO6S2
MW:
303.31
EINECS:
204-246-1
Product Categories:
  • Anilines, Aromatic Amines and Nitro Compounds
  • Organic acids
  • Intermediates of Dyes and Pigments
Mol File:
118-33-2.mol
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2-Naphthylamine-5,7-disulfonic acid Chemical Properties

Boiling point:
568.34℃[at 101 325 Pa]
Density 
1.769±0.06 g/cm3(Predicted)
vapor pressure 
0Pa at 25℃
pka
-0.91±0.40(Predicted)
Water Solubility 
229g/L at 15℃
InChI
InChI=1S/C10H9NO6S2/c11-7-1-2-9-6(3-7)4-8(18(12,13)14)5-10(9)19(15,16)17/h1-5H,11H2,(H,12,13,14)(H,15,16,17)
InChIKey
KZCSUEYBKAPKNH-UHFFFAOYSA-N
SMILES
C1(S(O)(=O)=O)=C2C(C=C(N)C=C2)=CC(S(O)(=O)=O)=C1
LogP
-1.85
CAS DataBase Reference
118-33-2(CAS DataBase Reference)
EPA Substance Registry System
1,3-Naphthalenedisulfonic acid, 6-amino- (118-33-2)
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Safety Information

RIDADR 
1759
HazardClass 
8
PackingGroup 
III
Toxicity
rat,LD50,oral,2gm/kg (2000mg/kg),"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1059, 1986.
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2-Naphthylamine-5,7-disulfonic acid Usage And Synthesis

Chemical Properties

White glossy long prismatic needle-like crystals, the crystals precipitated from water contain 5 molecules of crystal water. The solubility in water at 20°C is 23%. Its monosodium salt and monopotassium salt are commonly used in industry, both of which are soluble in water, and the salt solution has green fluorescence.

Uses

2-Naphthylamine-5,7-disulfonic acid is an intermediate for the preparation of J acid, bis-J acid, phenyl J acid and scarlet acid.

Hazard

Skin - Rabbit 2 mg/24h severe; Eye - Rabbit 0.75 mg/24h severe

Flammability and Explosibility

Not classified

Synthesis

2-Naphthylamine-5,7-disulfonic acid can be obtained by hydrolysis of 2-naphthylamine-1,5,7-trisulfonic acid. Add sulfuric acid, sodium sulfate and 2-naphthylamine-1,5,7-trisulfonic acid into water, keep warm at 110-120°C for 4 hours, cool and filter, and wash in sodium sulfate solution to obtain the product.

2-Naphthylamine-5,7-disulfonic acid Preparation Products And Raw materials

Raw materials

2-Naphthylamine-5,7-disulfonic acidSupplier

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