1-Hydroxy-2,1-benzoxaborolane Chemical Properties

Melting point:

95-100 °C

Boiling point:

237.2±43.0 °C(Predicted)

Density 

1.18±0.1 g/cm3(Predicted)

storage temp. 

Inert atmosphere,2-8°C

pka

7.01±0.20(Predicted)

form 

powder to crystal

color 

White to Almost white

BRN 

4333

CAS DataBase Reference

5735-41-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36-24/25

WGK Germany 

3

Hazard Note 

Irritant/Keep Cold

HS Code 

29349990

MSDS

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1-Hydroxy-2,1-benzoxaborolane Usage And Synthesis

Chemical Properties

Solid

Uses

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.

Definition

ChEBI: 1-hydroxy-2,1-benzoxaborole is a member of the class of benzoxaboroles that is 2,1-benzoxaborole in which the hydrogen attached to the boron atom is replaced by a hydroxy group.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 835, 1958 DOI: 10.1021/ja01537a021

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