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1,1'-DIANTHRIMIDE

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1,1'-DIANTHRIMIDE Basic information

Product Name:
1,1'-DIANTHRIMIDE
Synonyms:
  • 1,1’-iminobis-10-anthracenedione
  • 1,1’-iminodi-anthraquinon
  • 1,1-dianthrimid
  • anthraquinonylaminoanthraquinone
  • anthrimide
  • bis-(1-anthrachinonyl)amin
  • di-1,1’-anthrachinonylamin
  • DIANTHRAQUINONYLAMINE
CAS:
82-22-4
MF:
C28H15NO4
MW:
429.42
EINECS:
201-405-7
Product Categories:
  • Anthraquinones
  • Chloroanthraquine, etc.
Mol File:
82-22-4.mol
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1,1'-DIANTHRIMIDE Chemical Properties

Melting point:
300 °C
Boiling point:
544.01°C (rough estimate)
Density 
1.2950 (rough estimate)
refractive index 
1.6290 (estimate)
pka
-4.72±0.20(Predicted)
form 
powder to crystal
color 
Orange to Brown to Dark red
Merck 
14,690
CAS DataBase Reference
82-22-4(CAS DataBase Reference)
EPA Substance Registry System
9,10-Anthracenedione, 1,1'-iminobis- (82-22-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
RTECS 
CB7780000
HS Code 
2922.39.4500

MSDS

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1,1'-DIANTHRIMIDE Usage And Synthesis

Chemical Properties

Dark red powder

Uses

Determination of boron. 1,1'-Dianthrimide is used as a 0.02% solution in Concentrated H2SO4. The olive-green solution turns blue in the presence of boron. The blue solution has an absorption max at 620 nm. Also used in the determination of silicon.

Synthesis

1,1'-Dianthraquinonylamine , dianthrimide, is prepared by reacting 1-aminoanthraquinone with 1- chloroanthraquinone in nitrobenzene or water . Also from 1-aminoanthraquinone and 1-nitroanthraquinone .

Purification Methods

Crystallise anthrimide from chlorobenzene (red needles) or nitrobenzene (red rhombs). It is poorly soluble in organic solvents. [Eckert & Steiner Monatsh Chem 35 1129 1914.]

1,1'-DIANTHRIMIDESupplier

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