VINYLBENZYL ALCOHOL Chemical Properties

Boiling point:

101-102 °C/12 mmHg (lit.)

Density 

1.021 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.54(lit.)

Flash point:

202 °F

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

VINYLBENZYL ALCOHOL Usage And Synthesis

Uses

α?Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.

Uses

α-Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 3524, 1987 DOI: 10.1021/jo00392a006

General Description

α-Vinylbenzyl alcohol is an allyl alcohol derivative. Its isomerization reaction using a novel ternary catalyst system has been reported. The kinetic resolution of racemic α-vinylbenzyl alcohol by tungsten-catalyzed asymmetric epoxidation method has been repoorted. The coupling reaction of α-vinylbenzyl alcohol and aldehydes in the presence of RuCl₂(PPh₃)₃ catalyst and In(OAc)₃ as a co-catalyst in ionic liquids has been investigated. Etherification reaction of glycerol with α-vinylbenzyl alcohol in the presence of sulfonic catalyst immobilized on silica (SiO₂–SO₃H) has been reported.

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