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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Basic information

Product Name:
TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE
Synonyms:
  • tetrakis(acetonitrile)copper(I) hexa-fluorophosph
  • Tetrakis(acetonitrle)copper(I) Hexafluorophosphate
  • Tetrakis(acetonitrile)copper [Ⅰ] hexafluorophosphate
  • Tetrakis(acetonitrile)copper(I)hexafluorophosphate,98+%
  • tetrakis(acetonitrile)copper(I)
  • tetrakis(acetonitrile)copper hexa-fluorophosph
  • Tetrakis(acetonitrile)copper [] hexafluorophosphate
  • acetonitrile,copper(1+),hexafluorophosphate
CAS:
64443-05-6
MF:
C8H12CuF6N4P
MW:
372.72
Product Categories:
  • organometallic complex
  • Cu
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Copper
Mol File:
64443-05-6.mol
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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Chemical Properties

Melting point:
160 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
form 
solid
color 
white to light blue
Sensitive 
air sensitive, moisture sensitive
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
2926907090

MSDS

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TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATE Usage And Synthesis

Reaction

  1. Useful catalyst for the Ullmann synthesis.
  2. Catalytic asymmetric [2,3]-Sigmatropic rearrangement of sulfur ylides.
  3. Precatalyst for enantioselective N–H insertion reactions with diazoesters and anilines.

Uses

Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively.
It can also be used as a copper precursor:

  • For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.
  • To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].
  • To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.
  • For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

TETRAKIS(ACETONITRILE)COPPER (I) HEXAFLUOROPHOSPHATESupplier

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