tBuXPhos-Pd-G3
tBuXPhos-Pd-G3 Basic information
- Product Name:
- tBuXPhos-Pd-G3
- Synonyms:
-
- [2'-(Amino)[1,1'-biphenyl]-2-yl][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium
- [(2-Di-tert-butylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [t-BuXPhos Palladacycle]
- tBuXPhos Pd G3
- Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- tBuXPhos Pd G3 97%
- METHANESULFONATO(2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[T-BUXPHOSPALLADACYCLEGEN.3]
- Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato-κO)-
- CAS:
- 1447963-75-8
- MF:
- C42H58NO3PPdS
- MW:
- 794.38
- Product Categories:
-
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd
- Mol File:
- 1447963-75-8.mol
tBuXPhos-Pd-G3 Chemical Properties
- Melting point:
- 130-140°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- color
- yellow
- InChI
- InChI=1S/C29H45P.C12H9N.CH4O3S.Pd/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h13-21H,1-12H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
- InChIKey
- KKVLHKIBKWORMK-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C)(C(C)(C)C)C(C)(C)C
tBuXPhos-Pd-G3 Usage And Synthesis
Physical properties
tBuXPhos-Pd-G3 is in the form of a dark grey crystalline powder.
Uses
tBuXPhos Pd G3 may be used to synthesize 4-cyano-7-azaindole from 4-chloro-7-azaindole by cyanation reaction. It may also be used for the α-arylation reaction of acetate esters at room temperature.
Reactions
Mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.
General Description
tBuXPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuXPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
storage
tBuXPhos Pd G3 should be stored in an airtight, dry and low temperature.
tBuXPhos-Pd-G3Supplier
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- 027-027-87680032 18963957250
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tBuXPhos-Pd-G3(1447963-75-8)Related Product Information
- XPhos Pd G3
- XantPhos Pd G4
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- SPhos Palladacycle Gen. 4
- XPhos Pd G4
- Xantphos Pd G3
- BrettPhos Pd G3
- XPhos Pd G2
- RuPhos Pd G1 Methyl t--Butyl Ether Adduct
- SPhos Pd G2
- BrettPhosPalladacycle
- Palladacycle Gen. 3
- t-BuXphos Palladacycle Gen. 4
- RuPhos Palladacycle Gen. 4
- t-BuBrettPhos Palladacycle Gen. 3
- SPhos Pd G3
- SPhos Pd G1, Methyl t-Butyl Ether Adduct
- RuPhos Pd G2