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2-Hydroxydiphenylmethane

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2-Hydroxydiphenylmethane Basic information

Product Name:
2-Hydroxydiphenylmethane
Synonyms:
  • Benproperine Impurity 2
  • A-PHENYL-O-CRESOL
  • ALPHA-PHENYL-O-CRESOL
  • 2-BENZYLPHENOL
  • 2-HYDROXYDIPHENYLMETHANE
  • 2-HYDYOXYDIPHENYLMETHANE
  • 2-Benzylphenol,99%
  • 2-(phenylmethyl)-pheno
CAS:
28994-41-4
MF:
C13H12O
MW:
184.23
EINECS:
249-361-8
Product Categories:
  • Phenoles and thiophenoles
Mol File:
28994-41-4.mol
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2-Hydroxydiphenylmethane Chemical Properties

Melting point:
49-51 °C (lit.) 49-51 °C
Boiling point:
312 °C (lit.)
Density 
1.0120 (rough estimate)
refractive index 
nD20 1.59945
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
practically insoluble
form 
powder to crystal
pka
10.39±0.30(Predicted)
color 
White to Brown
Water Solubility 
practically insoluble
Merck 
14,1142
BRN 
2045725
CAS DataBase Reference
28994-41-4(CAS DataBase Reference)
NIST Chemistry Reference
Phenol, 2-(phenylmethyl)-(28994-41-4)
EPA Substance Registry System
Phenol, 2-(phenylmethyl)- (28994-41-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
29071990

MSDS

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2-Hydroxydiphenylmethane Usage And Synthesis

Chemical Properties

colorless to red-pink crystals

Uses

2-Benzylphenol was used as starting reagent in the synthesis of 2-benzylacetate. It was also used in the the synthesis of 6- and 8-benzyl derivatives of 2-(dialkylamino)chromones.

Synthesis Reference(s)

Synthesis, p. 803, 1977 DOI: 10.1055/s-1977-24589

Purification Methods

Distil 2-benzylphenol in a vacuum and recrystallise it from EtOH. It has a stable form with m ~52o and an unstable form with m 21o. [Beilstein 6 H 675, 6 IV 4628.]

2-Hydroxydiphenylmethane Preparation Products And Raw materials

Preparation Products

Raw materials

2-HydroxydiphenylmethaneSupplier

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