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Pyridine hydrofluoride

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Pyridine hydrofluoride Basic information

Product Name:
Pyridine hydrofluoride
Synonyms:
  • Pyridine hydrofluoride
  • PYRIDINIUM POLY(HYDROGEN FLUORIDE) COMPLEX (APPROX 70% HF:30% PYRIDINE W/W)
  • Hydrogen fluoride-pyridine, 20% HF
  • Hydrogen Fluoride Pyridine(55%/70%HF)
  • Hydrogen fluoride-py
  • Hydrogen Fluoride, 70wt.% in Pyridine
  • Hydrogen Fluoride, 55wt.% in Pyridine
  • Hydrogen fluoride pyridine 55%
CAS:
32001-55-1
MF:
C5H6FN
MW:
99.11
EINECS:
250-889-6
Product Categories:
  • bc0001
Mol File:
32001-55-1.mol
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Pyridine hydrofluoride Chemical Properties

Boiling point:
50°C 1mm
Density 
1.1 g/mL at 20 °C(lit.)
Flash point:
50°C/1mm
storage temp. 
-20°C Freezer, Under inert atmosphere
solubility 
sol CH2Cl2, MeCN, Et2O, THF, toluene, sulfolane.
form 
Liquid
color 
Clear pale yellow to light brown
Sensitive 
Moisture Sensitive
BRN 
4750151
InChI
InChI=1S/C5H5N.FH/c1-2-4-6-5-3-1;/h1-5H;1H
InChIKey
GRJJQCWNZGRKAU-UHFFFAOYSA-N
SMILES
C1=CC=NC=C1.F
CAS DataBase Reference
32001-55-1(CAS DataBase Reference)
EPA Substance Registry System
Pyridine hydrofluoride (32001-55-1)
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Safety Information

Hazard Codes 
T+,C
Risk Statements 
26/27/28-35-34
Safety Statements 
26-28-36/37/39-45-27
RIDADR 
UN 1790 8/PG 1
WGK Germany 
2
3-10
TSCA 
T
HazardClass 
8
PackingGroup 
II
HS Code 
29333999

MSDS

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Pyridine hydrofluoride Usage And Synthesis

Description

Pyridine hydrofluoride has a convenient, less volatile form of anhydrous HF with enhanced nucleophilicity.

Chemical Properties

clear pale yellow to light brown liquid

Uses

Pyridinium Poly(hydrogenfluoride) is used in the synthesis of analogues of antimitotic natural product curacin A. It is also an effective fluorinating agent.

Synthesis

?Pyridine hydrofluoride is prepared by condensation of anhydrous Hydrogen Fluoride into Pyridine at -78 °C, followed by gradual warming to rt; caution: highly exothermic.

Pyridine hydrofluoride Preparation Products And Raw materials

Preparation Products

Pyridine hydrofluorideSupplier

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