Basic information Reaction Safety Supplier Related

[Ru(bpz)3][PF6]2

Basic information Reaction Safety Supplier Related

[Ru(bpz)3][PF6]2 Basic information

Product Name:
[Ru(bpz)3][PF6]2
Synonyms:
  • [Ru(bpz)3][PF6]2
  • [Ru(bpz)3][PF6]2 AldrichCPR
  • [Ru(bpz)3][PF6]2 95%
  • Tris (2,2'-bipyrazine) ruthenium hexafluoroborate
  • TRIS(2,2'-BIPYRAZINE)RUTHENIUM(II)HEXAFLUOROPHOSPHATE,95%
  • Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95%
  • lambda2-ruthenium(2+) tris(2,2'-bipyrazine) bis(hexafluoro-lambda5-phosphanuide)
  • 2'-bipyrazine) ruthenium hexafluoroborate
CAS:
80907-56-8
MF:
C24H18F6N12PRu+
MW:
720.53
Mol File:
80907-56-8.mol
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[Ru(bpz)3][PF6]2 Chemical Properties

Melting point:
162-210°C (The MP data is a DECOMP) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
red
Sensitive 
air sensitive
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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[Ru(bpz)3][PF6]2 Usage And Synthesis

Reaction

  1. Endoperoxide synthesis by photocatalytic aerobic [2+2+2] cycloadditions.
  2. Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis. Facile synthesis of methylenebridged bis-1,3-dicarbonyl compounds.
  3. Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis.
  4. Photooxygenation of aryl cyclopropanes via visible light photocatalysis.

Uses

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

General Description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

[Ru(bpz)3][PF6]2Supplier

BeiJing Hwrk Chemicals Limted
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0757-86329057 18501085097
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sales3.gd@hwrkchemical.com
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Email
han_yajun@dctc.daicel.com
ShangHai YuanYe Biotechnology Co., Ltd.
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021-61312847 13636370518
Email
shyysw007@163.com
Bide Pharmatech Ltd.
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400-1647117 15221909166
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product02@bidepharm.com
Suzhou Laing Biological Technology Co., LTD
Tel
0512-62968256 18550502935
Email
export@laingbiotec.com