Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Basic information
- Product Name:
- Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
- Synonyms:
-
- Ir(4,6Fppy)3
- Ir(Fppy)3
- Tris(2-(4,6-difuorophenyl)pyridine)iridium(III)
- TRIS[2-(2,4-DIFLUOROPHENYL)PYRIDINE]IRIDIUM(III),95%
- 2-(2,4-difluorobenzene-6-id-1-yl)pyridine,iridium(3+)
- Tris[4,6-difluoro-2-(2-pyridyl)phenyl-C2,N]iridium(III)
- IR606, Tris[4,6-difluoro-2-(2-pyridyl)phenyl-C2,N]iridium(III)
- )pyridine]iridium(III)
- CAS:
- 387859-70-3
- MF:
- C33H18F6IrN3
- MW:
- 762.74
- Mol File:
- 387859-70-3.mol
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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Chemical Properties
- Melting point:
- 401 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- Powder
- color
- yellow
- Sensitive
- air sensitive
- λmax
- 347 nm
- InChI
- InChI=1S/3C11H6F2N.Ir/c3*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;/h3*1-4,6-7H;/q3*-1;+3
- InChIKey
- GJHHESUUYZNNGV-UHFFFAOYSA-N
- SMILES
- FC1C=C(F)C=[C-]2[Ir+3]34(N5=CC=CC=C5C5=C(C=C(F)C=[C-]35)F)(N3=CC=CC=C3C3=C(C=C(F)C=[C-]43)F)N3=CC=CC=C3C=12
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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Usage And Synthesis
Reaction
- Photoredox catalysis for trifluoromethylation of arenes and heteroarenes.
- Photocatalyst for C–F alkenylation coupling reactions between perfluoroarenes and alkynes.
Uses
Ir(dFppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α amino acids using visible light.
reaction suitability
core: iridium
reaction type: Photocatalysis
reagent type: catalyst
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Supplier
Beijing Beibaoled Technology Co., Ltd. Gold
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- 010-60271698; 18001249871
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Yunnan Precious Metals Laboratory Co., Ltd Gold
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- 871-15559856 15559856215
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- 0757-86329057 18934348241
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Energy Chemical
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- 021-021-58432009 400-005-6266
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Suzhou Laing Biological Technology Co., LTD
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- 0512-62968256 18550502935
- export@laingbiotec.com
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Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) (387859-70-3)Related Product Information
- Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III)
- Ir[dF(t-Bu)-ppy]3
- (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
- Iridium
- [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
- (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate
- Tris (2- (4-tert-butylphenyl) pyridine) iridium
- Ir[dF(Me)ppy]2(dtbbpy)PF6
- Ir(dFppy)3
- (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
- Ir[p-F(t-Bu)-ppy]3
- [Ir{dFCF3ppy}2(bpy)]PF6
- [Ir(dtbbpy)(ppy)2][PF6]
- Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
- Ir[dFppy]2(dtbbpy)PF6
- hexafluorophosphate
- Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
- Ir[p-F(Me)ppy]2(dtbbpy)PF6