(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Chemical Properties

Boiling point:

365.6±9.0 °C(Predicted)

Density 

0.95±0.1 g/cm3(Predicted)

Flash point:

>230 °F

storage temp. 

2-8°C

optical activity

[α]20/D 72±3°, c = 1% in diethyl ether

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

F 

10-21

MSDS

• Language:English Provider:SigmaAldrich

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE Usage And Synthesis

Uses

Reactant involved in organic synthesis reactions such as:

• Double allylboration for synthesis of fragments of tetrafibricin
• Anticancer cytotoxic monorhizopodin synthesis
• Annulation of cyclic allylsilanes
• Asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs

General Description

B-Methoxydiisopinocampheylborane (Ipc₂BOMe) is an organoborane compound, which is prepared from excess α-pinene, borane dimethylsulfide, and methanol via the formation of an intermediate diisocampheylborane. Ipc₂BOMe is used as a versatile reagent for the construction of C-C bonds in asymmetric synthesis.

(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE(85134-98-1)Related Product Information

• ISO-PROPYLCYCLOBUTANE
• Methoxydiethylborane
• (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
• (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
• Disiamylborane
• (1R)-(+)-CIS-PINANE
• (1R)-(+)-TRANS-PINANE
• 1-ETHYLCYCLOBUTANE