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BUTOCARBOXIM

Basic information Safety Supplier Related

BUTOCARBOXIM Basic information

Product Name:
BUTOCARBOXIM
Synonyms:
  • 3-METHYLTHIOBUTANONE O-METHYLCARBAMOYLOXIME
  • (2E)-2-(([(Methylamino)carbonyl]oxy)imino)-3-(methylsulfanyl)butane
  • 2-Butanone, 3-(methylthio)-, O-(N-methylcarbamoyl)oxime
  • 2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime
  • 2-Butanone,3-(methylthio)-,O-(N-methylcarbamoyl)oxime
  • 2-Methylthio-O-(N-methylcarbamoyl)-butanonoxim-3
  • BUTOCARBOXIM
  • DRAWIN
CAS:
34681-10-2
MF:
C7H14N2O2S
MW:
190.26
EINECS:
252-139-3
Product Categories:
  • A-BPesticides&Metabolites
  • AcaricidesAlphabetic
  • Alpha sort
  • B
  • BI - BZPesticides
  • Carbamates
  • Insecticides
  • Pesticides
  • Pesticides&Metabolites
Mol File:
34681-10-2.mol
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BUTOCARBOXIM Chemical Properties

Melting point:
25 °C
Density 
1.2118 (rough estimate)
vapor pressure 
1.1×10-2pa(20°C)
refractive index 
1.5690 (estimate)
Water Solubility 
35 g l-1 (20 °C)
pka
13.83±0.46(Predicted)
EPA Substance Registry System
2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime (34681-10-2)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
10-23/24/25-36-50/53
Safety Statements 
36/37-45-60-61
RIDADR 
2757
WGK Germany 
3
RTECS 
EL9215000
HazardClass 
6.1(b)
PackingGroup 
III
Hazardous Substances Data
34681-10-2(Hazardous Substances Data)
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BUTOCARBOXIM Usage And Synthesis

Uses

Butocarboxim is a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees in agric ulture.

Uses

Labelled Butocarboxim, a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees i n agriculture.

Metabolic pathway

Butocarboxin is a structural isomer of aldicarb. Butoxycarboxim is the sulfur oxidation (sulfone) product of butocarboxim. Limited information is available to describe the degradation and metabolic fate of these two compounds. As with aldicarb, oxidation of the sulfur molecule of butocarboxim to butocarboxim sulfoxide and butoxycarboxim is the primary photolytic and metabolic reaction in soils, plants and animals (Scheme 1).

Degradation

Butocarboxim (1) is stable to hydrolytic degradation (pH 5-7, up to 50 °C, PM) and is stable under UV light irradiation. It degrades under strong acidic and alkaline conditions.
Butoxycarboxim (2) is susceptible to alkaline hydrolysis (DT50 values of 500, 18 and 16 days in pH 5, 7 and 9, respectively, PM). It is also stable under UV light irradiation.

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