Basic information Safety Supplier Related

(R)-1-(Naphthalen-1-yl)ethanol

Basic information Safety Supplier Related

(R)-1-(Naphthalen-1-yl)ethanol Basic information

Product Name:
(R)-1-(Naphthalen-1-yl)ethanol
Synonyms:
  • (r)-(+)-α-methyl-1-naphthalenemethanol
  • R-(-)-1-(1-Napthalenyl)ethanol
  • R-(-)-1-(1-naphthalenyl)ethanol
  • (R)-(+)-1-(1-NAPHTHYL)ETHANOL
  • (R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL
  • (1R)-1-(1-naphthyl)ethan
  • (1R)-1-(1-naphthyl)ethanol
  • 1-Naphthalenemethanol, α-methyl-, (αR)-
CAS:
42177-25-3
MF:
C12H12O
MW:
172.22
Mol File:
42177-25-3.mol
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(R)-1-(Naphthalen-1-yl)ethanol Chemical Properties

Melting point:
47-49 °C(lit.)
alpha 
78 º (C=1 IN MEOH)
Boiling point:
316.0±11.0 °C(Predicted)
Density 
1.113±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
14.29±0.20(Predicted)
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29062990

MSDS

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(R)-1-(Naphthalen-1-yl)ethanol Usage And Synthesis

Chemical Properties

White solid

Uses

(R)?-?1-?(Naphthalen-?1-?yl)?ethanol is a coupling reagent used in the synthesis of ferrocene aminophosphoxazoline ligands.

Purification Methods

Purify the alcohol by recrystallisation from Et2O/pet ether, Et2O, hexane [Balfe et al. J Chem Soc 797 1946, IR, NMR: Theisen & Heathcock J Org Chem 53 2374 1988, see also Fredga et al. Acta Chem Scand 11 1609 1957]. The RS-alcohol [57605-95-5] has m 63-65o, 65-66o from hexane. [Beilstein 6 III 3034, 6 IV 4346.]

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