(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties

Melting point:

134-136°C

Boiling point:

817.0±65.0 °C(Predicted)

alpha 

-134o (C=1 IN METHANOL)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

pka

13.35±0.40(Predicted)

form 

Powder

color 

white to off-white

optical activity

[α]20/D -134°, c = 1 in methanol

Safety Information

Risk Statements 

36/37/38

Safety Statements 

26-36/37/39

WGK Germany 

3

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)(169689-05-8)Related Product Information

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