O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE Chemical Properties

Melting point:

62-65 °C (lit.)

Boiling point:

87-90 °C/40 mmHg (lit.)

Density 

0.849±0.06 g/cm3(Predicted)

Flash point:

54°C

storage temp. 

2-8°C

solubility 

freely sol hexane, chloroform, and most organic solvents; insol water.

pka

4.75±0.70(Predicted)

form 

solid

Appearance

Colorless to off-white Solid-Liquid Mixture

Water Solubility 

Hydrolyzes in water.

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Sensitive 

Moisture Sensitive

BRN 

2424306

InChI

InChI=1S/C6H17NOSi/c1-6(2,3)9(4,5)8-7/h7H2,1-5H3

InChIKey

SSUCKKNRCOFUPT-UHFFFAOYSA-N

SMILES

NO[Si](C(C)(C)C)(C)C

CAS DataBase Reference

41879-39-4(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

RIDADR 

UN 3259 8/PG 2

WGK Germany 

3

F 

10-21

TSCA 

No

HazardClass 

8

PackingGroup 

III

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE Usage And Synthesis

Physical properties

mp 62–65°C; bp 87–90°C/40 mmHg.

Uses

O-(tert-Butyldimethylsilyl)hydroxylamine (tert-butyldimethylsilyl-O-hydroxylamine)is used to induce the cleavage, during solid supported synthesis of hydroxamic acids. It also finds it uses as a chemical additive and an intermediate.

Uses

O-(tert-Butyldimethylsilyl)hydroxylamine (tert-butyldimethylsilyl-O-hydroxylamine) may be used to induce the cleavage, during solid supported synthesis of hydroxamic acids.

Preparation

the reagents are most conveniently prepared by treatment of hydroxylamine hydrochloride with ethylenediamine in dichloromethane, followed by the appropriate chlorosilane.A two-step procedure using ammonia in place of ethylenediamine has also been reported.

O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE(41879-39-4)Related Product Information

• DIMETHYLSILANE
• HYDROXYLAMINE
• TERT-BUTYLDIMETHYLSILANOL
• IFLAB-BB F2108-0016
• T-BUTYLDIMETHYLSILANE
• O-(TRIMETHYLSILYL)HYDROXYLAMINE
• O-(TERT-BUTYLDIMETHYLSILYL)HYDROXYLAMINE