ChemicalBook > Product Catalog > Catalyst and Auxiliary > Precious Metal Catalysts > Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) Basic information
- Product Name:
- Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
- Synonyms:
-
- CHLORO{1,3-BIS[2,6-DI-I-PROPYLPHENYL]-4,5-DIHYDROIMIDAZOL-2-YLIDENE}GOLD(I),98%SIPRAUCL
- Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
- Chloro{1,3-bis[2,6-bis(1-methylethyl)phenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)
- Chloro {1,3-bis [2,6-diisopropyl
- CAS:
- 852445-84-2
- MF:
- C27H38AuClN2
- MW:
- 623.02357
- Mol File:
- 852445-84-2.mol
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Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) Chemical Properties
- form
- Powder
- color
- white
- Sensitive
- air sensitive
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Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) Usage And Synthesis
Reaction
Catalyst for the rearrangement of allylic acetates
Uses
As an organometallic compound, Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) can be used as an important intermediate to synthesize various organometallic catalysts. It is also an important precious metal catalyst.
Preparation
The reaction of 1,3-bis(mesityl)imidazolium chloride with [AuCl(tht)] in CH2Cl2 was carried out for 15 minutes. Afterward, Potassium carbonate was added to the reaction system. Finally, Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) can be obtained through purification.
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