Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) Chemical Properties

storage temp. 

2-8°C, protect from light, stored under nitrogen

form 

Powder

color 

white

Sensitive 

air sensitive

InChI

InChI=1S/C27H38N2.Au.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-14,18-21H,15-16H2,1-8H3;;1H/q;+1;/p-1

InChIKey

KBTULXWTYFHSDZ-UHFFFAOYSA-M

SMILES

[Au](Cl)[C]1N(C2=C(C(C)C)C=CC=C2C(C)C)CCN1C1=C(C(C)C)C=CC=C1C(C)C |^1:2|

Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) Usage And Synthesis

Reaction

Catalyst for the rearrangement of allylic acetates  

Uses

As an organometallic compound, Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) can be used as an important intermediate to synthesize various organometallic catalysts. It is also an important precious metal catalyst.

Preparation

The reaction of 1,3-bis(mesityl)imidazolium chloride with [AuCl(tht)] in CH2Cl2 was carried out for 15 minutes. Afterward, Potassium carbonate was added to the reaction system. Finally, Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I) can be obtained through purification.

Chloro{1,3-bis[2,6-di-i-propylphenyl]-4,5-dihydroimidazol-2-ylidene}gold(I)(852445-84-2)Related Product Information

• 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISO&