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Didodecyldimethylammonium bromide

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Didodecyldimethylammonium bromide Basic information

Product Name:
Didodecyldimethylammonium bromide
Synonyms:
  • n-dodecyl-n,n-dimethyl-1-dodecanaminiubromide
  • N-Dodecyl-N,N-diMethyldodecan-1-aMiniuM broMide
  • DDAB)DidodecyldiMethylaMMoniuM bro
  • (Di-n-dodecyl)diMethylaMMoniuM broMide, 98+%
  • DidodecyldiMethylaMMoniuM broMide (DDAB)
  • DidodecyldiMethylaMMoniuM broMide 98%
  • DIMETHYLDIDODECYLAMMONIUM BROMIDE
  • DI-N-DODECYLDIMETHYLAMMONIUM BROMIDE
CAS:
3282-73-3
MF:
C26H56BrN
MW:
462.63
EINECS:
221-923-7
Product Categories:
  • Ammonium Bromides (Quaternary)
  • Quaternary Ammonium Compounds
Mol File:
3282-73-3.mol
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Didodecyldimethylammonium bromide Chemical Properties

Melting point:
157-162 °C(lit.)
Density 
1.0463 (rough estimate)
refractive index 
1.5260 (estimate)
solubility 
ethanol: 0.1 g/mL, clear, colorless
form 
Crystalline Powder
color 
White to off-white
Water Solubility 
Soluble in hot and cold water.
Sensitive 
Hygroscopic
BRN 
3576662
Stability:
Stable. Hygroscopic. Incompatible with strong oxidizing agents, moisture.
CAS DataBase Reference
3282-73-3(CAS DataBase Reference)
EPA Substance Registry System
Didodecyl dimethyl ammonium bromide (3282-73-3)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
3
TSCA 
Yes
HS Code 
29239000

MSDS

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Didodecyldimethylammonium bromide Usage And Synthesis

Chemical Properties

white powder

Uses

(Di-n-dodecyl)dimethylammonium bromide is used as a phase transfer catalyst. It is also used as floor disinfectant. Further, it acts as surface-active agent.

Uses

Didodecyldimethylammonium bromide (DDAB) is a double-chain cationic surfactant.
Possible applications:
DDAB can be employed as a co-surfactant to synthesize well-defined multilamellar vesicular silica with an adjustable number of layers.
As a surfactant to synthesize gold nanoclusters and nanocubes.
It forms supersaturated reverse micelles and microemulsions that act as organized reaction microenvironments for the synthesis of barium sulfate.
Calcium montmorillonite can be modified by DDAB through direct ion-exchange to synthesize thermally stable organoclay.

Purification Methods

Recrystallise the salt from acetone, acetone/ether mixture, then from ethyl acetate, wash with ether and dry it in a vacuum oven at 60o [Chen et al. J Phys Chem 88 1631 1984, Rupert et al. J Am Chem Soc 107 2628 1985, Halpern et al. J Am Chem Soc 108 3920 1986, Allen et al. J Phys Chem 91 2320 1987]. [Beilstein 4 IV 801.]

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