CHLOROTRIS(TRIMETHYLSILYL)SILANE Chemical Properties

Melting point:

50-52 °C (lit.)

Boiling point:

93°C/1.8mmHg(lit.)

Density 

0.877 g/mL at 25 °C

Flash point:

87 °F

form 

powder to lump

color 

White to Almost white

Hydrolytic Sensitivity

8: reacts rapidly with moisture, water, protic solvents

Safety Information

Hazard Codes 

F,C,Xn,Xi

Risk Statements 

11-29-34-67-65-48/20-36/37/38-63

Safety Statements 

16-26-36/37/39-43-45-7/8-62-36/37-Neverusewater.

RIDADR 

UN 2925 4.1/PG 2

WGK Germany 

3

HS Code 

2931.90.9010

HazardClass 

4.1/8

PackingGroup 

II

MSDS

• Language:English Provider:SigmaAldrich

CHLOROTRIS(TRIMETHYLSILYL)SILANE Usage And Synthesis

Uses

Super Silyl Protecting Groups

Used for:

• Insertion into a P-P bond
• Diastereoselective aldol and cascade reactions
• Preparation of hypersilyl substituted monophosphines and diphosphines

General Description

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

CHLOROTRIS(TRIMETHYLSILYL)SILANE(5565-32-2)Related Product Information

• Bis(trimethylsilyl)trifluoroacetamide
• Trisilane
• CHLOROTRIS(TRIMETHYLSILYL)SILANE
• TRIS(TRIMETHYLSILYL)SILANE
• Chlorotrimethylsilane
• 3-Chloropropyltriethoxysilane