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N-TERT-BUTYLFORMAMIDE

Basic information Safety Supplier Related

N-TERT-BUTYLFORMAMIDE Basic information

Product Name:
N-TERT-BUTYLFORMAMIDE
Synonyms:
  • N-tert-Butylformamide,97%
  • N-tert-butylmethanamide
  • N-tert-Butylformamide
  • n-(1,1-dimethyl)formamide(nlm)
  • n-(1,1-dimethylethyl)-formamid
  • N-(1,1-dimethylethyl)formamide
  • n-(tert-butyl)-formamid
  • n-t-butylformamide
CAS:
2425-74-3
MF:
C5H11NO
MW:
101.15
EINECS:
219-369-6
Product Categories:
  • Amides
  • Carbonyl Compounds
  • Organic Building Blocks
Mol File:
2425-74-3.mol
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N-TERT-BUTYLFORMAMIDE Chemical Properties

Melting point:
16 °C(lit.)
Boiling point:
202 °C(lit.)
Density 
0.903 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.433(lit.)
Flash point:
203 °F
pka
16.47±0.23(Predicted)
form 
clear liquid
color 
Colorless to Light yellow
BRN 
1738869
CAS DataBase Reference
2425-74-3(CAS DataBase Reference)
EPA Substance Registry System
Formamide, N-(1,1-dimethylethyl)- (2425-74-3)
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Safety Information

Safety Statements 
23-24/25
WGK Germany 
3
RTECS 
LQ1450000
8
HS Code 
2924.19.1150
Hazardous Substances Data
2425-74-3(Hazardous Substances Data)

MSDS

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N-TERT-BUTYLFORMAMIDE Usage And Synthesis

Uses

N-tert-Butylformamide was used to investigate the ability of low molecular weight amides to function as non-aqueous amphiphile self-assembly media.

General Description

N-tert-Butylformamide forms nanostructure due to segregation of the molecules into polar and non-polar domains, analogous to amphiphile self-assembly.

Safety Profile

A poison by intravenous route. When heated to decomposition it emits toxic fumes of NOx

Purification Methods

If the IR indicates some hydrolysis, then dissolve it in Et2O, wash it with 20% aqueous Na2CO3, dry it (MgSO4), filter and fractionate it. Collect the fraction that solidifies on cooling and recrystallise it from Et2O at low temperature if necessary. [Emmons J Am Chem Soc 79 5753 1957, Beilstein 4 III 324, 4 IV 661.]

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