DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Chemical Properties

Melting point:

280 °C (dec.)(lit.)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Soluble in ethanol, benzene, and ethereal solvents.

form 

Crystalline Powder

color 

Yellow to orange

Sensitive 

Air & Moisture Sensitive

InChI

InChI=1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;

InChIKey

KFQYTZDYGOBBOE-UHFFFAOYSA-N

SMILES

P(C1C=CC=CC=1C)(C1C=CC=CC=1C)(C1C=CC=CC=1C)[Pd+2]([Cl-])([Cl-])P(C1C=CC=CC=1C)(C1C=CC=CC=1C)C1C=CC=CC=1C

Safety Information

Risk Statements 

53

Safety Statements 

22-24/25

WGK Germany 

3

TSCA 

No

HS Code 

28439000

MSDS

• Language:English Provider:SigmaAldrich

DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) Usage And Synthesis

Chemical Properties

Yellow to orange crystalline powder

Uses

suzuki reaction

Uses

Dichlorobis(tri-o-tolylphosphine)palladium(II) is used in reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides, coupling reaction of aryl bromides with vinylic acetates.

General Description

Dichlorobis(tri-o-tolylphosphine)palladium(II) is a useful catalyst for C-C and C-N coupling reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium

DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)(40691-33-6)Related Product Information

• Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
• DICHLORO(N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE)PALLADIUM(II)
• DICHLOROBIS(INDENYL)TITANIUM(IV)
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• DICHLOROBIS(CHLORODI-TERT-BUTYLPHOSPHINE) PALLADIUM (II)
• Bis(tricyclohexylphosphine)palladium(II) Dichloride
• dichlorobis(di-tert-butylphenylphosphine)palladium(II)
• BIS(TRIPHENYLPHOSPHINE)COPPE
• DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II)
• Palladium chloride
• Phosphine
• DIPHENYL(O-TOLYL)PHOSPHINE
• Tri(o-tolyl)phosphine
• BIS(O-TOLYL)PHOSPHINE
• DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
• CIS-DICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)PALLADIUM(II)