TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Chemical Properties

Melting point:

126-128 °C(lit.)

Flash point:

1 °F

storage temp. 

2-8°C

form 

crystal

color 

yellow

Water Solubility 

Reacts with water

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Sensitive 

Moisture Sensitive

InChI

InChI=1S/2C4H8O.4ClH.Ti/c2*1-2-4-5-3-1;;;;;/h2*1-4H2;4*1H;/q;;;;;;+4/p-4

InChIKey

LXWBMENBONGPSB-UHFFFAOYSA-J

SMILES

[Ti](Cl)(Cl)(Cl)Cl.C1COCC1.C1COCC1

CAS DataBase Reference

31011-57-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

C

Risk Statements 

14-34-37

Safety Statements 

26-36/37/39-45

RIDADR 

UN 2925 4.1/PG 2

WGK Germany 

3

F 

3-10

TSCA 

No

HazardClass 

8

PackingGroup 

II

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

TETRACHLOROBIS(TETRAHYDROFURAN)TITANIUM(IV) Usage And Synthesis

Chemical Properties

The reaction of tetrachlorodi(tetrahydrofuran)titanium(IV) and magnesium in tetrahydrofuran under argon protection gives [Ti(MgCl)2(THF)]2. It reacts with magnesium directly in a nitrogen atmosphere to give TiN(MgCl)2(THF), which can then be reacted with iodine, via the ITiN(MgCl)2 intermediate, to produce Ti=N(MgCl). Stannous chloride can also reduce it to produce TiCl3(THF)3 and green [TiCl2(THF)4][SnCl5(THF)]: 2 TiCl4(THF)2 + SnCl2 → [trans-TiCl2(THF)4][SnCl5(THF)] + TiCl3(THF)3

Uses

Titanium(IV) chloride tetrahydrofuran complex can be used as a catalyst in intermolecular hydroamination reactions.

reaction suitability

core: titanium
reagent type: Lewis acid
reagent type: catalyst

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