2,4-Dichlorobenzyl chloride
2,4-Dichlorobenzyl chloride Basic information
- Product Name:
- 2,4-Dichlorobenzyl chloride
- Synonyms:
-
- 2,4-dichloro-1-(chloromethyl)-benzen
- 2,4-Dichloro-1-(chloromethyl)benzene
- 2,4-dichloro-1-chloromethyl-benzene
- -2,4-Trichlorotoluene
- benzene,2,4-dichloro-1-(chloromethyl)-
- Toluene, alpha2,4-trichloro-
- toluene,α,2,4-trichloro-
- α,2,4-trichlorotoluene
- CAS:
- 94-99-5
- MF:
- C7H5Cl3
- MW:
- 195.47
- EINECS:
- 202-381-0
- Product Categories:
-
- Aromatics
- Miscellaneous Reagents
- Econazole Nitrate
- Aromatic Halides (substituted)
- Mol File:
- 94-99-5.mol
2,4-Dichlorobenzyl chloride Chemical Properties
- Melting point:
- -2.6 °C (lit.)
- Boiling point:
- 248 °C (lit.)
- Density
- 1.407 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.576(lit.)
- Flash point:
- >230 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Oily Liquid
- color
- Clear colorless to very light yellow
- BRN
- 387220
- InChI
- InChI=1S/C7H5Cl3/c8-4-5-1-2-6(9)3-7(5)10/h1-3H,4H2
- InChIKey
- IRSVDHPYXFLLDS-UHFFFAOYSA-N
- SMILES
- C1(CCl)=CC=C(Cl)C=C1Cl
- LogP
- 4.08
- CAS DataBase Reference
- 94-99-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 2,4-dichloro-1-(chloromethyl)-(94-99-5)
- EPA Substance Registry System
- Benzene, 2,4-dichloro-1-(chloromethyl)- (94-99-5)
Safety Information
- Hazard Codes
- C,N
- Risk Statements
- 34-37-50/53-22
- Safety Statements
- 26-36/37/39-45-61-60
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- F
- 19
- Hazard Note
- Corrosive
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29036990
MSDS
- Language:English Provider:2,4-Dichlorobenzoylchloride
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
2,4-Dichlorobenzyl chloride Usage And Synthesis
Chemical Properties
clear colorless to very light yellow oily liquid
Uses
2,4-Dichlorobenzyl chloride was used as starting reagent for the synthesis of series of novel 1,2,4-triazolium derivatives.
Uses
2,4-Dichlorobenzyl chloride is a reagent used in the addition of dichlorobenzene.
Synthesis
1777-82-8
94-99-5
GENERAL STEPS: 2,4-dichlorobenzyl alcohol (17.7 g, 0.1 mol), dichloromethane (30 mL), and N,N-dimethylformamide (DMF, 1 mL) were added to a 100 mL round-bottomed flask, followed by the slow dropwise addition of phosphorus trichloride (4.68 g, 0.034 mol). The reaction mixture was heated to reflux temperature (60-80°C) and the reaction lasted for 2-3 hours. The progress of the reaction was monitored by thin layer chromatography (TLC) until the complete disappearance of the raw material. After completion of the reaction, 2,4-dichlorobenzyl chloride (17.99 g, 92% yield) was purified by distillation.
References
[1] Patent: CN106117028, 2016, A. Location in patent: Paragraph 0053; 0054; 0055; 0056
2,4-Dichlorobenzyl chloride Preparation Products And Raw materials
Preparation Products
Raw materials
2,4-Dichlorobenzyl chlorideSupplier
- Tel
- 027-83855381 15827508403
- xiaozhan0503@163.com
- Tel
- 18678041314 18765609661
- 2547772582@qq.com
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
- Tel
- 4006356688 18621169109
- market03@meryer.com
- Tel
- 400-6106006
- saleschina@alfa-asia.com
2,4-Dichlorobenzyl chloride(94-99-5)Related Product Information
- Choline chloride
- 2-Chloro-5-chloromethylpyridine
- Ammonium chloride
- Diethylstilbestrol
- Benzyl chloride
- Calcium chloride
- 4,4'-Bis(chloromethyl)-1,1'-biphenyl
- Polyvinyl chloride
- Mepiquat chloride
- alpha,alpha'-Dichloro-p-xylene
- 4-Chlorobenzyl chloride
- Benzyl chloroformate
- 2,4-Dichlorobenzyl alcohol
- Sodium chloride
- BENZAL CHLORIDE
- 2,4,6-Trichlorobenzoyl chloride
- Methylene Chloride
- 2,3-DICHLOROBENZYL CHLORIDE,2,3-DICHLOROBENZYL CHLORIDE 99%