2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL CAS#: 787618-22-8

ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

Basic information Reaction Safety Supplier Related

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Basic information

Product Name:

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

Synonyms:

2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, min.98%
dicyclohexyl(2',6'-diisopropoxybiphenyl-2-yl)phosphine
{2-[2,6-bis(propan-2-yloxy)phenyl]phenyl}dicyclohexylphosphane
Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine
98% RuPhos
2-DicyclohexylphosphiNA-2',6'-diisopropoxy-1,1'-biphenyl
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,RuPhos
Dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane

CAS:

787618-22-8

MF:

C30H43O2P

MW:

466.64

EINECS:

616-653-5

Product Categories:

Achiral Phosphine
Aryl Phosphine
Buchwald Ligands Series
Buchwald Ligands&Precatalysts

Mol File:

787618-22-8.mol

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2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Chemical Properties

Melting point:: 123-124°C
Boiling point:: 551.7±40.0 °C(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form: Powder
color: white
Sensitive: Air Sensitive
InChI: InChI=1S/C30H43O2P/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25/h11-13,18-25H,5-10,14-17H2,1-4H3
InChIKey: MXFYYFVVIIWKFE-UHFFFAOYSA-N
SMILES: P(C1=CC=CC=C1C1=C(OC(C)C)C=CC=C1OC(C)C)(C1CCCCC1)C1CCCCC1

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Safety Information

Hazard Codes: Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36/37/39
WGK Germany: 3
TSCA: No
HS Code: 29310099

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2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Usage And Synthesis

Reaction

Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines.
Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides.
Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation.
A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles,
Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst.
Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides.
Ligand used for the palladium-catalyzed coupling of alkyl boronates.

Uses

suzuki reaction

Uses

Bulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborate?s with electron-poor aryl bromides.

Uses

2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl is the ligand used for the palladium-catalyzed coupling of alkyl boronates.

reaction suitability

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYLSupplier

Xinxiang Runyu Material Co., Ltd. Gold

Tel: 166-166-37336996 15690792173
Email: chenxi.song@runvmat.com

Zhengzhou HQ Material Co., Ltd. Gold

Tel: 0371-67759225 13526468238
Email: sales@hqmat.com

Shaanxi Rock New Materials Co., Ltd. Gold

Tel: 0917-8888777, 3380777,18691786767; 15619786767
Email: xuya@bjrock.com

Puyang Huicheng Electronic Material Co. Ltd. Gold

Tel: 0393-0393-0393-8910800 15039333257
Email: info@huichengchem.com

BeiJing Greenchem Technology Co.,Ltd. Gold

Tel: 131-21959385 18804271668
Email: chemrocking@bjgreenchem.com

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