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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL

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2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Basic information

Product Name:
2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL
Synonyms:
  • 2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, min.98%
  • dicyclohexyl(2',6'-diisopropoxybiphenyl-2-yl)phosphine
  • {2-[2,6-bis(propan-2-yloxy)phenyl]phenyl}dicyclohexylphosphane
  • Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine
  • 98% RuPhos
  • 2-DicyclohexylphosphiNA-2',6'-diisopropoxy-1,1'-biphenyl
  • 2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl,RuPhos
  • Dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane
CAS:
787618-22-8
MF:
C30H43O2P
MW:
466.64
EINECS:
616-653-5
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts
Mol File:
787618-22-8.mol
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2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Chemical Properties

Melting point:
123-124°C
Boiling point:
551.7±40.0 °C(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Powder
color 
white
Sensitive 
Air Sensitive
InChIKey
MXFYYFVVIIWKFE-UHFFFAOYSA-N
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Safety Information

Hazard Codes 
Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36/37/39
WGK Germany 
3
TSCA 
No
HS Code 
29310099
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2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL Usage And Synthesis

Reaction

  1. Versatile Ligand for the Pd-catalyzed coupling of secondary arylamines and alkylamines.
  2. Ligand used for the Pd-catalyzed Negishi cross-coupling reaction of (hetero)arylchlorides.
  3. Synthesis of ladder-type π-conjugated heteroacenes via palladium-catalyzed double N-arylation and intramolecular O-arylation.
  4. A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles,
  5. Versatile ligand used for the Pd-catalyzed C-N coupling reaction of secondary aryl- and alkyl-amines at low temperature with the Pd precatalyst.
  6. Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
  7. Ligand for the palladium-catalyzed trifluoromethylation of hindered aryl chlorides.
  8. Ligand used for the palladium-catalyzed coupling of alkyl boronates.



Uses

suzuki reaction

Uses

Bulky phosphine ligand used in a palladium-catalyzed cross-coupling of aminoethyltrifluoroborate?s with electron-poor aryl bromides.

Uses

2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl is the ligand used for the palladium-catalyzed coupling of alkyl boronates.

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