ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Chloro(1,5-cyclooctadiene)rhodium(I) dimer
Chloro(1,5-cyclooctadiene)rhodium(I) dimer Basic information
- Product Name:
- Chloro(1,5-cyclooctadiene)rhodium(I) dimer
- Synonyms:
-
- Bis(1,5-cyclohexadiene)-mu,mu'-dichlorodirhodium
- Bis(cycloocta-1,5-diene)dichlorodirhodium
- Chloro(1,5-cyclooctadiene)rhodium dimer
- Dichloro-bis-1,5-cyclooctadiene dirhodium
- Di-mu-chlorobis(1,5-cyclooctadiene)dirhodium
- di-mu-chlorobis[(1,2,5,6-eta)-1,5-cyclooctadiene]di-rhodiu
- Rhodium 1,5-cyclooctadiene chloride dimer
- Rhodium chloro(cycloocta-1,5-diene) dimer
- CAS:
- 12092-47-6
- MF:
- C16H24Cl2Rh2
- MW:
- 493.08
- EINECS:
- 235-157-6
- Product Categories:
-
- Morpholines/Thiomorpholines ,Isoxazoles
- Rh
- Rh (Rhodium) Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Synthetic Organic Chemistry
- Transition Metal Compounds
- organometallic complexes
- Mol File:
- 12092-47-6.mol
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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Chemical Properties
- Melting point:
- 243 °C (dec.) (lit.)
- Density
- 1.94[at 20℃]
- vapor pressure
- 0Pa at 25℃
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in chloroform, dichloromethane, and methanol. Sparingly soluble in most common solvents.
- form
- Crystals or Crystalline Powder
- color
- Orange to orange-brown
- Water Solubility
- 1.56g/L at 20℃
- Sensitive
- Air Sensitive & Hygroscopic
- Exposure limits
- ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 - Stability:
- hygroscopic
- LogP
- 3.16 at 20℃
- NIST Chemistry Reference
- Bis(1,5-cyclooctadienerhodium chloride)(12092-47-6)
- EPA Substance Registry System
- Rhodium, di-.mu.-chlorobis[(1,2,5,6-.eta.)-1,5-cyclooctadiene]di- (12092-47-6)
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MSDS
- Language:English Provider:Chloro(1,5-cyclooctadiene)rhodium(I) dimer
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Chloro(1,5-cyclooctadiene)rhodium(I) dimer Usage And Synthesis
Reaction
- Catalyst for coupling 1,3-dienes with activate methylene compounds.
- Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones.
- Rhodium source for asymmetric reductive aldol reaction.
- Cis-hydroboration of terminal alkynes.
- Rhodium source for [5 + 2] additions.
- Highly enantioselective for [2+2+2] carbocyclization reactions.
- Enantioselective hydroboration of cyclopropenes.
Chemical Properties
orange crystals
Uses
It is a widely used precursor to homogeneous catalysts. This is a chiral catalyst capable of asymmetrically hydrogenating certain prochiral alkenes. Chloro(1,5-cyclooctadiene)rhodium(I) dimer is also used in the synthesis of other metal ligands for use in catalysis.
Uses
Chloro(1,5-cyclooctadiene)rhodium(I) dimer ([Rh(COD)Cl]2) can be:
- Employed for the synthesis of rhodium complex of heterocyclic carbenes (NHCs).
- Modified and coated on the surface of ferrite magnetic nanoparticles for catalyzing hydroformylation reaction of olefins.
- Used for the synthesis of triple-layer structure to be used as a ring-opening polymerization catalyst.
- As an effective catalyst for dehydrogenation of amine-borane adducts (hydrogen storage materials) such as ammonia-borane.
General Description
This product has been enhanced for catalytic efficiency.
Flammability and Explosibility
Not classified
Chloro(1,5-cyclooctadiene)rhodium(I) dimer Preparation Products And Raw materials
Raw materials
Chloro(1,5-cyclooctadiene)rhodium(I) dimerSupplier
LaaJoo Gold
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com
Shaanxi Rock New Materials Co., Ltd. Gold
- Tel
- 0917-8888777, 3380777,18691786767; 15619786767
- xuya@bjrock.com
Aikon International Limited Gold
- Tel
- 025-66113011 18112977050
- cb6@aikonchem.com
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. Gold
- Tel
- 025-66113011 18112977050
- cb6@aikonchem.com
Sinocompound Catalysts Co., Ltd. Gold
- Tel
- 0512-67216630 67216634
- sales@sinocompound.com
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Chloro(1,5-cyclooctadiene)rhodium(I) dimer(12092-47-6)Related Product Information
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- Potassium chloride
- Rhodium
- Ammonium chloride
- Calcium chloride
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