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Terbutryn

Basic information Safety Supplier Related

Terbutryn Basic information

Product Name:
Terbutryn
Synonyms:
  • TERBUTREX
  • TERBUTRYN
  • TERBUTRYNE
  • TERNIT
  • SUNTER
  • n-(1,1-dimethylethyl)-n'-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine
  • PREBANE
  • PREBANE(R)
CAS:
886-50-0
MF:
C10H19N5S
MW:
241.36
EINECS:
212-950-5
Product Categories:
  • Pyridazines
  • Agro-Products
  • Amines
  • Bases & Related Reagents
  • Heterocycles
  • Isotope Labelled Compounds
  • HERBICIDE
  • TA - TEPesticides&Metabolites
  • Alpha sort
  • Herbicides
  • Pesticides&Metabolites
  • Q-ZAlphabetic
  • Nucleotides
  • Sulfur & Selenium Compounds
  • Triazines
  • Alphabetic
Mol File:
886-50-0.mol
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Terbutryn Chemical Properties

Melting point:
104-105°C
Boiling point:
154-160°C
Density 
1.45
refractive index 
1.5500 (estimate)
Flash point:
2 °C
storage temp. 
APPROX 4°C
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Powder
pka
4.03±0.10(Predicted)
color 
White
Water Solubility 
0.0025 g/100 mL
BRN 
611817
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
886-50-0(CAS DataBase Reference)
NIST Chemistry Reference
Terbutryn(886-50-0)
EPA Substance Registry System
Terbutryn (886-50-0)
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Safety Information

Hazard Codes 
Xi,N,Xn,F
Risk Statements 
36-50/53-20/21/22-11
Safety Statements 
26-60-61-36/37-16
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
RTECS 
XY4725000
Hazardous Substances Data
886-50-0(Hazardous Substances Data)
Toxicity
LC50 (96-hour) for rainbow trout 3 mg/L, bluegill sun?sh 4 mg/L, carp 4 mg/L and perch 4 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 2,500 mg/kg (Hartley and Kidd, 1987), 2,045 mg/kg (RTECS, 1985).
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Terbutryn Usage And Synthesis

Description

Terbutin is a systemic and conductive herbicide, which can be used for pre-emergence and post-emergence weeding, and the effective period in the soil is 3-10 weeks. It is mainly used in winter wheat, barley, sorghum, sunflower, potatoes, peas, soybeans, peanuts and other crop fields to control perennial ryegrass, ryegrass and autumn germinating chickweed, marigolds, poppies, kangaroo, crabgrass, foxtail Wait.

Chemical Properties

solid

Uses

Selective herbicide for control of annual broad-leaved and grass weeds in wheat.

Uses

A triazine herbicide.

Uses

A labelled triazine herbicide.

Definition

ChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by a tert-butylamino and an ethylamino group at positions 2 and 4 respectively.

Synthesis

Cyanuric chloride reacts with ter-butylamine to generate 2,4-dichloro-6-tert-butylamino-1,3,5-triazine; then reacts with ethylamine to generate 2-chloro-4-ethylamino-6-tertiary Butylamino-1,3,5-triazine, and finally reacts with methyl mercaptan to generate Terbutryn.

Environmental Fate

Plant. In plants, the methylthio group is oxidized to hydroxy derivatives and by dealkylation of the side chains. Residual activity in soil is limited to approximately 3–10 weeks (Hartley and Kidd, 1987).

Terbutryn Preparation Products And Raw materials

Raw materials

TerbutrynSupplier

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